104827-27-2

Basic information

• Product Name: 14-bromo-1-phenyl-tetradec-1-yne
• Synonyms: 14-bromo-1-phenyl-tetradec-1-yne
• CAS NO: 104827-27-2
• Molecular Weight: 349.354
• Mol File: 104827-27-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 14-bromo-1-phenyl-tetradec-1-yne(CAS DataBase Reference)
• NIST Chemistry Reference: 14-bromo-1-phenyl-tetradec-1-yne(104827-27-2)
• EPA Substance Registry System: 14-bromo-1-phenyl-tetradec-1-yne(104827-27-2)

Safety Data

• Hazardous Substances Data: 104827-27-2(Hazardous Substances Data)

Upstream product

• 3344-70-5 1,12-dibromododecane 
• 536-74-3 phenylacetylene 

Downstream Products

• 88337-00-2 methyl 15-(p-iodophenyl)pentadecanoate 
• 80479-93-2 15-(p-iodophenyl)pentadecanoic acid 
• 88336-99-6 ω-phenyl pentadecanoic acid methyl ester 
• 104827-29-4 15-Phenyl-pentadecanenitrile 
• 40228-93-1 ω-phenyl pentadecanoic acid 
• 104827-28-3 (14-Bromo-tetradecyl)-benzene 

Relevant articles and documents

Kumada-Corriu reactions of alkyl halides with alkynyl nucleophiles

Pd2(dba)3-Ph3P-catalyzed Kumada-Corriu coupling reactions of unactivated alkyl bromides or iodides with an alkynyl nucleophile furnish Csp-Csp3 bond formation. Alkynyl nucleophiles can be alkynyllithiums or the corresponding Grignard reagents. The superior performance of Ph3P ligand over the trialkylphosphine ligands indicates that this cross-coupling reaction may be a reductive-elimination-controlled process.