1048954-71-7Relevant articles and documents
Iterative molecular assembly based on the cation-pool method. Convergent synthesis of dendritic molecules
Nokami, Toshiki,Ohata, Kousuke,Inoue, Masafumi,Tsuyama, Hiroaki,Shibuya, Akito,Soga, Kazuya,Okajima, Masayuki,Suga, Seiji,Yoshida, Jun-Ichi
, p. 10864 - 10865 (2008)
An iterative method for molecular assembly has been developed based on the cation-pool method using (trimethylsilyl)diphenylmethane as a building block. The silyl group works as both an activating group of the benzene ring in the Friedel-Crafts type reaction and an electroauxiliary in the subsequent low temperature anodic oxidation to generate dendritic diarylcarbenium ions, which were well characterized by low-temperature NMR spectroscopy. The convergent synthesis of dendritic molecules has been achieved by repeating the sequence. Copyright