10580-65-1Relevant articles and documents
Alcoholysis of Epoxides Catalyzed by Tetracyanoethylene and Dicyanoketene Acetals
Masaki, Yukio,Miura, Tsuyoshi,Ochiai, Masahito
, p. 195 - 205 (1996)
A typical π-acid tetracyanoethylene and capto-dative olefin dicyanoketene acetals were found to catalyze stereospecific alcoholysis of epoxides at the ambient temperature to 50°C in good yields. Mildness and significant chemoselectivity of the catalysts were demonstrated by intactness of tetrahydropyranyl ether and ethylene acetal groups. A novel regioselectivity associated with anchimeric assistance of the ethereal group on the side chain was observed in the ring opening reaction of the 1,2-disubstituted epoxides.
Synthesis and study of the lubricating properties of some thiiranes
Allakhverdiev,Akperov,Mustafaev,Farzaliev
, p. 214 - 218 (2007/10/03)
A series of novel thiiranes were synthesized, and their lubricating properties were studied. It has been found that they improve the antiscuff and antiwear properties of gear oils and therefore can be used as additives. The relation between the structure of the synthesized thiiranes and their lubricating activity was revealed.