1058345-44-0Relevant articles and documents
Intermolecular chemo- and regioselective aromatic C-H amination of alkoxyarenes promoted by rhodium nitrenoids
Arai, Kenta,Ueda, Yoshihiro,Morisaki, Kazuhiro,Furuta, Takumi,Sasamori, Takahiro,Tokitoh, Norihiro,Kawabata, Takeo
, p. 2264 - 2267 (2018)
Intermolecular aromatic C(sp2)-H amination promoted by neutral rhodium nitrenoids has been developed. The reactions proceeded with various oxygen-substituted arenes (1.5 equiv.) in a chemo- and regioselective manner. The aromatic C(sp2)-H amination took place at the para position of the oxygen substituent in the presence of benzylic C(sp3)-H bonds and/or C(sp3)-H bonds α to ethereal oxygen.