834-14-0Relevant articles and documents
High Ethylene Selectivity in Methanol-to-Olefin (MTO) Reaction over MOR-Zeolite Nanosheets
Guan, Yejun,Hu, Bingwen,Huang, Ju,Jiang, Jingang,Li, Chao,Lu, Kun,Ma, Yanhang,Ren, Li,Wu, Peng,Xu, Hao
, p. 6258 - 6262 (2020)
Precisely controlled crystal growth endows zeolites with special textural and catalytic properties. A nanosheet mordenite zeolite with a thickness of ca. 11 nm, named as MOR-NS, has been prepared using a well-designed gemini-type amphiphilic surfactant as
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Goldschmidt,Larsen
, p. 429 (1904)
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Paterno
, p. 589 (1871)
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Plasmon heating mediated Friedel-Crafts alkylation of anisole using supported AuNP@Nb2O5catalysts
Dos Santos, Carolina G.,Marquez, Daniela T.,Crites, Charles-Oneil L.,Netto-Ferreira, Jose Carlos,Scaiano, Juan C.
, p. 427 - 431 (2017)
Two different hybrid materials composed of gold nanoparticles (AuNPs) supported on either commercial niobium oxide HY 340 or mesoporous niobium oxide catalyzed the Friedel-Crafts alkylation of anisole by benzyl chloride. Excitation of the surface plasmon of the supported AuNPs allowed the reaction to occur at lower temperatures by acting as an alternative heat source. The localized heating produced via plasmon excitation permitted the acid catalyzed reaction to occur - at the Lewis acid sites on the Nb2O5support - at 80?°C while thermal-dark reactions using a conventional heat source, required temperatures of 120?°C or higher. The catalytic activity of the tested hybrid materials decreased with storage time. However, the deactivation showed to be reversible upon lyophilisation indicating that the nature of the deactivation could be due to water adsorption.
Development of highly efficient Friedel-Crafts alkylations with alcohols using heterogeneous catalysts under continuous-flow conditions
Kobayashi, Shū,Koumura, Nagatoshi,Masuda, Koichiro,Okamoto, Yukiko,Onozawa, Shun-Ya
, p. 24424 - 24428 (2021/07/29)
The development of Friedel-Crafts alkylations with alcohols under continuous-flow conditions using heterogeneous catalysts is reported. The reactivities and durabilities of the examined catalysts were systematically investigated, which showed that montmorillonite clay is the best catalyst for these reactions. A high turnover frequency of 9.0 × 102h?1was recorded under continuous-flow conditions, and the continuous operation was successfully maintained over one week.
METHOD FOR PRODUCING ARENE COMPOUNDS AND ARENE COMPOUNDS PRODUCED BY THE SAME
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Paragraph 0075, (2021/06/26)
Provided is a method for producing (alkyl)arene compounds represented by Formulae 3-1, 3-2, and 3-3 by the Friedel-Crafts alkylation reaction of alkyl halide compounds and arene compounds using organic phosphine compounds as a catalyst.