5267-47-0

Basic information

• Product Name: Acetamide, N-[(4-methoxyphenyl)phenylmethyl]-
• CAS NO: 5267-47-0
• Molecular Formula: C16H17NO2
• Molecular Weight: 255.316
• Mol File: 5267-47-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Acetamide, N-[(4-methoxyphenyl)phenylmethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-[(4-methoxyphenyl)phenylmethyl]-(5267-47-0)
• EPA Substance Registry System: Acetamide, N-[(4-methoxyphenyl)phenylmethyl]-(5267-47-0)

Safety Data

• Hazardous Substances Data: 5267-47-0(Hazardous Substances Data)

Upstream product

• 1309582-72-6 N,N'-sulfonyl bis-[(4-methoxyphenyl)(phenyl)methanamine] 
• 108-24-7 acetic anhydride 
• 171364-79-7 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 87100-32-1 2-[chloro(phenyl)methyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 108-86-1 bromobenzene 
• 1185842-25-4 N-[(4-Methoxylphenyl)(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]acetamide 
• 867182-05-6 N-[phenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]acetamide 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 60-35-5 acetamide 
• 720-44-5 1-(4-methoxyphenyl)-1-phenylmethanol 
• 75-05-8 acetonitrile 
• 75-36-5 acetyl chloride 
• 834-14-0 p-benzylanizole 

Relevant articles and documents

Air-stable Bis(pentamethylcyclopentadienyl) Zirconium Perfluorooctanesulfonate as an Efficient and Recyclable Catalyst for the Synthesis of N-substituted Amides

Bis(pentamethylcyclopentadienyl) zirconium perfluorooctanesulfonate is an air-stable and water-tolerant Lewis acid. This complex exhibited good thermal stability and high solubility in polar organic solvents. The compound showed relatively strong acidity, with an acid strength of 0.8Ho≤3.3, and high catalytic efficiency for the synthesis of N-substituted amides via the reaction of carboxylic acids with amines, the Ritter reaction of nitriles with alcohols, and the amination of alcohols with amides. Moreover, the complex had good reusability. This catalytic system affords a simple and efficient way to synthesize N-substituted amides.

Bis-sulfamyl imines: Potent substrates for asymmetric additions of arylboroxines under rhodium catalysis

Bis-sulfamyl imines are shown to be potentially ideal substrates for rhodium-catalysed asymmetric additions of arylboron nucleophiles as they show: (i) near perfect enantioselectivities (11 examples, 98-99+% ee), (ii) good to excellent diastereoselectivities (10-32:1 rac:meso), and (iii) high functional group tolerance in removal of the low molecular weight protecting group via mild heating in aqueous pyridine.

Molecular iodine-catalysed amidation reaction of secondary benzylic and allylic alcohols with carboxamides or sulfonamides

A highly efficient method for the C-N bond formation via 2 mol% of molecular iodine-catalysed amidation reaction of benzylic and allylic alcohols with carboxamides or sulfonamides in MeCN is described, giving the corresponding substituted amides and allyl