106201-03-0

Basic information

• Product Name: Benzene, [(2-methylcyclopentyl)sulfonyl]-
• CAS NO: 106201-03-0
• Molecular Formula: C12H16O2S
• Molecular Weight: 224.324
• Mol File: 106201-03-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-methylcyclopentyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-methylcyclopentyl)sulfonyl]-(106201-03-0)
• EPA Substance Registry System: Benzene, [(2-methylcyclopentyl)sulfonyl]-(106201-03-0)

Safety Data

• Hazardous Substances Data: 106201-03-0(Hazardous Substances Data)

Upstream product

• 39984-84-4 hex-5-en-1-yl(phenyl)sulfane 
• 64740-90-5 1-cyclopenten-1-yl phenyl sulfone 
• 693-89-0 1-methylcyclopent-1-ene 
• 1119-51-3 bromopentene 
• 19169-90-5 bromomethylphenylsulfone 
• 108-98-5 thiophenol 
• 96-37-7 methyl-cyclopentane 
• 193097-39-1 6-chloro-6-phenylsulfinyl-1-hexene 
• 125115-14-2 1-chloro-1-phenylsulfanyl-5-hexene 
• 132398-39-1 cis-2-methylcyclopentyl phenyl sulfoxide 
• 128916-69-8 (1-Bromo-hex-5-ene-1-sulfonyl)-benzene 
• 110434-51-0 cis-1-methyl-2-(phenylthio)cyclopentane 
• 132398-38-0 6-chloro-6-phenylsulfonyl-1-hexene 
• 187835-82-1 6-Iodohexylsulfonyl benzene 

Downstream Products

• 106201-03-0 1-benzenesulfonyl-2-methylcyclopentane 

Relevant articles and documents

Generation and intramolecular cyclization of α-sulfinyl and α-sulfonyl radicals

α-Phenylsulfinyl and α-Phenylsulfonyl radicals are generated by the reactions of α-chlorosulfoxides and α-chlorosulfones with tributyltin hydride, respectively. High reaction concentration (0.2 M) is required to ensure efficient generations of these radic

Applications of highly enantioenriched alcohols bearing a phenylthio group in the preparation of ring compounds. The two-pot synthesis of an enantiopure spiroacetal pheromone bearing three chiral centers

The new chiron (S)-6-phenylthio-2-hexanol (3) was prepared in high enantiomeric excess by baker's yeast reduction of the corresponding ketone. Enantioenriched alcohols 1, 2 and 3, prepared previously by a similar procedure, or their racemic counterparts, were transformed into ring closed compounds 5-methyl-2-(phenylthio)tetrahydrofuran (9), 6-methyl-2- (phenylthio)tetrahydropyran (10), 2-methyl-1-phenylsulfonyl cyclopropane (14), cyclobutane (15), cyclopentane (16), and a bee pheromone, (2S,6R,8S)- 2,8-dimethyl-1,7-dioxaspiro[5.5]undecane (20).

α-Sulfonyl radical initiated intramolecular tandem radical cyclization

Suitable derivatives of hex-5-enyl α-sulfonyl radical undergo cyclization to produce complex cyclic systems by a multiple radical chain mechanism.