1067883-66-2

Basic information

• Product Name: (2',6'-dimethylbiphenyl-4-yl)phenyl-methanone
• Synonyms: (2',6'-dimethylbiphenyl-4-yl)phenyl-methanone
• CAS NO: 1067883-66-2
• Molecular Weight: 286.373
• Mol File: 1067883-66-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2',6'-dimethylbiphenyl-4-yl)phenyl-methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2',6'-dimethylbiphenyl-4-yl)phenyl-methanone(1067883-66-2)
• EPA Substance Registry System: (2',6'-dimethylbiphenyl-4-yl)phenyl-methanone(1067883-66-2)

Safety Data

• Hazardous Substances Data: 1067883-66-2(Hazardous Substances Data)

Upstream product

• 131086-39-0 4-benzoylphenyl 4-methylbenzenesulfonate 
• 100379-00-8 2,6-dimethylbenzene boronic acid 
• 134-85-0 4-chlorobenzophenone 
• 83887-62-1 4-benzoylphenyl methane sulfonate 

Relevant articles and documents

Remarkably effective phosphanes simply with a PPh2 moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses

Chemical equation presented Expanding the horizons of ArPPh2: New applications of triarylphosphane ligands are presented. The Pd-L1 and Pd-L2 complexes offer exceptionally high activity in Suzuki-Miyaura cross-couplings of aryl chlorides. The extremely congested synthesis of tetraortho-substituted biaryl compounds is achieved for the first time by simply using triarylphosphane ligands.

Suzuki-Miyaura coupling of aryl tosylates catalyzed by an array of indolyl phosphine-palladium catalysts

A family of indolyl phosphine ligands was applied to Suzuki-Miyaura cross-coupling of aryl tosylates. Catalyst loading can be reduced to 0.2 mol % for coupling of nonactivated aryl tosylate. A challenging example for room temperature coupling is realized. The scope of this highly active Pd/L2 system can be extended to other boron nucleophiles, including trifluoroborate salts and boronate esters. The ligand structural comparisons toward the reactivity in tosylate couplings are also described.