106877-28-5

Basic information

• Product Name: Benzenamine, 2-(nonafluorobutyl)-
• CAS NO: 106877-28-5
• Molecular Formula: C10H6F9N
• Molecular Weight: 311.15
• Mol File: 106877-28-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzenamine, 2-(nonafluorobutyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 2-(nonafluorobutyl)-(106877-28-5)
• EPA Substance Registry System: Benzenamine, 2-(nonafluorobutyl)-(106877-28-5)

Safety Data

• Hazardous Substances Data: 106877-28-5(Hazardous Substances Data)

Upstream product

• 423-39-2 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane 
• 615-43-0 2-iodophenylamine 
• 354-64-3 Pentafluoroethyl iodide 
• 62-53-3 aniline 

Downstream Products

• 181059-76-7 2-(2,2,3,3,4,4,4-heptafluoro-1,1-diphenylbutyl)aniline 
• 181059-80-3 1-(2-Aminophenyl)-1,1-diethoxyheptafluorobutane 
• 217474-47-0 1-(2-Aminophenyl)-1-ethoxyoctafluorobutane 
• 200274-52-8 1-(2-Aminophenyl)heptafluorobutan-1-one 
• 311350-82-0 2-[2,2,3,3,4,4,4-heptafluoro-1,1-bis-(2-thienyl)butyl]aniline 
• 181059-81-4 1-(4-Aminophenyl)-1,1-diethoxyheptafluorobutane 

Relevant articles and documents

Benign Perfluoroalkylation of Aniline Derivatives through Photoredox Organocatalysis under Visible-Light Irradiation

In this work, we present a room- or solar-light-initiated transition-metal-free radical homolytic aromatic substitution (HAS) reaction of aniline derivatives with perfluoroalkyl moieties employing perfluoroalkyl halides as readily available perfluoroalkyl

Radical fluoroalkylation reactions of (hetero)arenes and sulfides under red light photocatalysis

Fluoroalkylation reactions of (hetero)aromatics have been accomplished through the low-power illumination from red LEDs (λmax = 635 nm) of commercially available perfluoroalkyl iodides RF-I and phthalocyanine zinc salt as photocatalyst in MeCN?:?DMF solvent mixture. This methodology has been extended to the perfluorobutylation of sulfides. As far as we are concerned, this is the first report on a perfluoroalkylation reaction of (hetero)aromatics and sulfides under red-light photocatalysis.

Synthesis of aminophenyl and methoxyphenyl perfluoroalkyl ketones

The title compounds are obtained by direct hydrolysis of the corresponding 2/4-perfluoroalkyl-substituted anilines and anisoles by the system AcOH/HBr/H2O/Al2O3. A two-step preparation of 2/4-perfluoroacylanilines involves the treatment of the 2/4-perfluoroalkylaniline with sodium ethoxide followed by hydrolysis of the resultant diethyl acetal with hydriodic acid.