107777-49-1

Basic information

• Product Name: [1,1'-Biphenyl]-2,2'-diol, 6,6'-dimethoxy-
• CAS NO: 107777-49-1
• Molecular Formula: C14H14O4
• Molecular Weight: 246.263
• Mol File: 107777-49-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [1,1'-Biphenyl]-2,2'-diol, 6,6'-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-Biphenyl]-2,2'-diol, 6,6'-dimethoxy-(107777-49-1)
• EPA Substance Registry System: [1,1'-Biphenyl]-2,2'-diol, 6,6'-dimethoxy-(107777-49-1)

Safety Data

• Hazardous Substances Data: 107777-49-1(Hazardous Substances Data)

Upstream product

• 57234-28-3 1-methoxy-3-(methoxymethoxy)benzene 
• 27974-34-1 1,6-Dimethoxy-dibenzo[1,4]dioxin 
• 7664-41-7 ammonia 

Downstream Products

• 718635-36-0 2,2'-bis(N,N-dimethylthiocarbamoyloxy)-6,6'-diphenyl-1,1'-biphenyl 
• 169057-75-4 2,2'-dimethoxy-6,6'-diphenyl-1,1'-biphenyl 
• 271249-45-7 2,2'-dihydroxy-6,6'-diphenyl-1,1'-biphenyl 
• 32750-01-9 6,6'-dimethyl-2,2'-biphenyldiol 
• 189299-64-7 (1,11-Dimethoxy-6-thioxo-5,7-dioxa-6λ⁵-phospha-dibenzo[a,c]cyclohepten-6-yl)-((S)-1-phenyl-ethyl)-amine 

Relevant articles and documents

Synthesis of Optically Pure 3,3′-Disubstituted-1,1′-Bi-6-Methoxy-2-Phenol (BIPhOL) Derivatives via Diastereomeric Resolution

A new protocol for the enantioselective synthesis of 3,3′-disubstituted-1,1′-bi-6-methoxy-2-phenol (BIPhOL) derivatives is described. Diastereomeric resolution of racemic BIPhOL boronic acid using a boronic acid moiety as a resolving group generated two diastereomers and subsequent Suzuki-Miyaura coupling reaction of the resulting diastereomers with aryl halides provided BIPhOL derivatives without any loss of enantioselectivity. In addition, the absolute stereochemistry of chiral BIPhOL was determined by comparison of the optical rotation with the reported value.

Synthesis of axially chiral compounds using diastereomeric resolution of racemic-boronic acids

The present invention refers to a portion of the preferred embodiment tax [mik[mik] - biphenyl boronic acid compounds that prevent an axial chirality stereochemical isomerism quality pipe acid; axial chiral biphenyl boronic acid intermediates in synthesizing method number bath using a novel method and axial chiral compound are disclosed. (by machine translation)