32750-01-9

Basic information

• Product Name: [1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI)
• Synonyms: [1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI);2,2'-Bi(3-methylphenol);2,2'-Bi[3-methylphenol];3,3'-Dimethyl-2,2'-biphenol;6,6'-Dimethyl-1,1'-biphenyl-2,2'-diol
• CAS NO: 32750-01-9
• Molecular Formula: C₁₄H₁₄O₂
• Molecular Weight: 214.26
• Product Categories: BIPHENYL
• Mol File: 32750-01-9.mol
• Article Data: 22

Chemical Properties

• Melting Point: 164 °C
• Boiling Point: 322.9±37.0 °C(Predicted)
• Appearance: /
• Density: 1.163±0.06 g/cm3(Predicted)
• PKA: 9.30±0.35(Predicted)
• CAS DataBase Reference: [1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI)(32750-01-9)
• EPA Substance Registry System: [1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI)(32750-01-9)

Safety Data

• Hazardous Substances Data: 32750-01-9(Hazardous Substances Data)

Usage

General Description

[1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI) is a chemical compound with the molecular formula C14H14O2. It is also known as 2,2'-dimethyl-1,1'-biphenyl-2,2'-diol. This organic compound consists of a biphenyl structure with two hydroxyl groups attached at the 2,2' positions and two methyl groups at the 6, 6' positions. It is often used as a building block in the synthesis of various organic compounds and pharmaceuticals. The properties and applications of this compound make it useful in the fields of chemistry and medicinal chemistry. However, it is important to handle this compound with caution due to its potential health hazards and toxicity.

Upstream product

• 154170-22-6 2,2'-dimethoxy-6,6'-dimethyl-1,1'-biphenyl 
• 86560-87-4 2,2'-diamino-6,6'-dimethylbiphenyl 
• 111412-13-6 6,6′-dimethyl-1,1′-biphenyl-2,2′-bis(carboxaldehyde) 
• 685108-73-0 4,4'-di-tert-butyl-6,6'-dimethylbiphenyl-2,2'-diol 
• 685108-71-8 2,7-di-tert-butyl-5,10-dihydro-[1]benzopyrano[5,4,3-cde]benzopyran-5,10-dione 
• 685108-72-9 4,4'-di-tert-butyl-6,6'-bis(hydroxymethyl)biphenyl-2,2'-diol 
• 1625-91-8 4,4'-di-tert-butylbiphenyl 
• 63992-30-3 2,2'-dihydroxy-4,4'-bis(tert-butyl)biphenyl 
• 570-24-1 2-Methyl-6-nitroaniline 
• 55153-02-1 2,2'-dinitro-6,6'-dimethyl-1,1'-biphenyl 
• 41085-43-2 2-bromo-3-nitrotoluene 
• 107777-49-1 2,2’-dihydroxy-6,6’-dimethoxy-1,1’-biphenyl 
• 169057-68-5 2,2'-bis(trifluoromethanesulfonyloxy)-6,6'-dimethoxy-1,1'-biphenyl 
• 5437-38-7 3-methyl-2-nitrobenzoic acid 

Downstream Products

• 10489-16-4 (R)-2,2'-dihydroxy-6,6'-dimethylbiphenyl 
• 10489-16-4 (S)-6,6'-dimethyl-[1,1'-diphenyl]-2,2'-diphenol 
• 1268524-63-5 4,4'-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(oxy)bis(methylene)bis(1-benzyl-1H-1,2,3-triazole) 
• 59517-24-7 6,6'-dimethyl-[1,1'-biphenyl]-2,2'-diyl dibenzoate 

Relevant articles and documents

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Hexafluoroisopropanol-Enabled Copper-Catalyzed Asymmetric Halogenation of Cyclic Diaryliodoniums for the Synthesis of Axially Chiral 2,2′-Dihalobiaryls

An efficient asymmetric halogenation of cyclic diaryliodonium salts is demonstrated, which gives access to a wide range of axially chiral 2,2′-dihalobiaryls in good to excellent yields and with excellent enantioselectivities. The use of CuX with chiral bisoxazoline ligand and tetrabutylammonium halides in the unique solvent of hexafluoroisopropanol (HFIP) led to the best results in the process. The axially chiral 2,2′-dihalobiaryls can be transformed into a number of enantiopure chiral ligands that could be potentially useful in asymmetric catalysis.

Macromolecular helicity induction and memory in a poly(biphenylylacetylene) bearing an ester group and its application to a chiral stationary phase for high-performance liquid chromatography

An optically inactive poly(biphenylylacetylene) bearing an ester group at the 4′-position of the pendants formed a preferred-handed helical conformation and biased axial chirality in the pendants through a noncovalent interaction with a chiral alcohol, both of which were retained (memorized) even after removal of the chiral alcohol. The chiral stationary phase for high-performance liquid chromatography, prepared by coating the polymer with macromolecular helicity memory on silica gel, showed good chiral recognition ability towards various racemates.