107994-99-0

Basic information

• Product Name: (R)-3-((R)-1-Methyl-2-oxo-2-phenyl-ethyl)-cyclohexanone
• CAS NO: 107994-99-0
• Molecular Weight: 230.307
• Mol File: 107994-99-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (R)-3-((R)-1-Methyl-2-oxo-2-phenyl-ethyl)-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-((R)-1-Methyl-2-oxo-2-phenyl-ethyl)-cyclohexanone(107994-99-0)
• EPA Substance Registry System: (R)-3-((R)-1-Methyl-2-oxo-2-phenyl-ethyl)-cyclohexanone(107994-99-0)

Safety Data

• Hazardous Substances Data: 107994-99-0(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 95837-63-1 (Z)-tert-butyldimethyl((1-phenylprop-1-en-1-yl)oxy)silane 
• 66323-99-7 trimethyl[(Z)-(1-phenyl-1-propenyl)oxy]silane 
• 93-55-0 1-phenyl-propan-1-one 
• 37471-46-8 1-phenyl-1-trimethylsiloxypropene 
• 94287-27-1 tert-butyldimethyl((1-phenylprop-1-en-1-yl)oxy)silane 

Relevant articles and documents

Indium-trichloride catalyzed Michael reaction of silyl enol ethers with α,β-unsaturated carbonyl compounds under neat condition

In the presence of a catalytic amount of indium (III) trichloride (InCl3) (20 mol%), ketene silyl enol ethers react quickly with α, β- unsaturated ketones and esters to afford the corresponding Michael adducts in moderate to good yields. Indium(III) trichloride can be recovered and reused without decrease in yields.

Stereoselective Michael additions of titanium "ate" complexes of ketone and ester enolates

The conjugate addition of Ti "ate" complexes of ketone and ester enolates to α,β-unsaturated carbonyl compounds was studied. The reaction was found to be highly regio- and stereoselective. Compared to the lithium enolates, ketone enolate Ti complexes show

Electrogenerated acid-catalyzed Michael reaction of enol silyl ethers and ketene silyl acetals to α,β-unsaturated carbonyl compounds

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