37471-46-8

Basic information

• Product Name: Silane, trimethyl[(1-phenyl-1-propenyl)oxy]-
• Synonyms: trimethyl-(1-phenylprop-1-enyloxy)silane;Silane,trimethyl[(1-phenyl-1-propenyl)oxy];trimethyl[(1-phenylpropenyl)oxy]-silane;propiophenone trimethylsilyl enol ether;(1-phenylprop-1-enyloxy)trimethylsilane;1-trimethylsiloxy-1-phenyl-1-propene
• CAS NO: 37471-46-8
• Molecular Formula: C12H18OSi
• Molecular Weight: 206.36
• Mol File: 37471-46-8.mol
• Article Data: 31

Chemical Properties

• Boiling Point: 40 °C(Press: 0.1 Torr)
• Density: 0.915±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Silane, trimethyl[(1-phenyl-1-propenyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[(1-phenyl-1-propenyl)oxy]-(37471-46-8)
• EPA Substance Registry System: Silane, trimethyl[(1-phenyl-1-propenyl)oxy]-(37471-46-8)

Safety Data

• Hazardous Substances Data: 37471-46-8(Hazardous Substances Data)

Upstream product

• 7449-74-3 N-methyl-N-trimethylsilylacetamide 
• 93-55-0 1-phenyl-propan-1-one 
• 98-86-2 acetophenone 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 100-52-7 benzaldehyde 
• 49750-22-3 1-(trimethylsilyl)vinylmagnesium bromide 
• 39623-95-5 1-phenylprop-1-enyl acetate 
• 400-53-3 trimethylsilyl trifluoroacetate 
• 51666-96-7 1-phenyl-2-(trimethylsilyl)-2-propen-1-ol 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 6493-83-0 2-methoxy-1-phenyl-propan-1-one 
• 137502-11-5 4-(1-benzoylethyl)-2,3-dichloro-4-hydroxycyclobut-2-enone 
• 105619-05-4 1,3-bis(methoxycarbonyl)-4-(1-methyl-2-oxo-2-phenylethyl)-1,4-dihydropyridine 
• 107994-99-0 (R)-3-((S)-1-Methyl-2-oxo-2-phenyl-ethyl)-cyclohexanone 
• 107994-99-0 (R)-3-((R)-1-Methyl-2-oxo-2-phenyl-ethyl)-cyclohexanone 
• 129139-66-8 3-(1-Methyl-2-oxo-2-phenyl-ethyl)-cyclohexanone 
• 55991-71-4 4-Methyl-5-phenyl-2,3-dihydrofuran-2,3-dione 
• 28403-86-3 1-phenyl-2-(phenylthio)propan-1-one 
• 56011-31-5 3-bromo-2-methyl-1-phenylpropan-1-one 
• 62509-81-3 3-methoxy-2-methyl-1-phenylpropan-1-one 
• 91-03-2 3-dimethylamino-2-methyl-1-phenyl-propan-1-one 
• 116409-45-1 (anti)-S-ethyl 3,4-dimethyl-5-oxo-5-phenylpentanethioate 
• 116409-45-1 (syn)-S-ethyl 3,4-dimethyl-5-oxo-5-phenylpentanethioate 
• 116409-49-5 S-t-butyl 4-methyl-5-oxo-5-phenyl-pentanethioate 

Relevant articles and documents

Borane-Catalyzed Direct Asymmetric Vinylogous Mannich Reactions of Acyclic α,β-Unsaturated Ketones

Herein, we report that, by using chiral bicyclic bisborane catalysts, we have achieved the first highly regio-, diastereo-, and enantioselective direct asymmetric vinylogous Mannich reactions of acyclic α,β-unsaturated ketones. The strong Lewis acidity and steric bulk of the bisborane catalysts were essential for the observed high yields and selectivities.

Three-Component Coupling of Acyl Fluorides, Silyl Enol Ethers, and Alkynes by P(III)/P(V) Catalysis

We report herein on the phosphine-catalyzed hydrovinylation reaction by three-component coupling of acyl fluorides, silyl enol ethers, and alkynoates. The key to the success of the reaction is the formal transmetalation between pentacoordinate P(V) species (i.e., fluorophosphorane) and a silyl enol ether, which allows for C-C bond formation between the polarity-mismatched sites. The bond formation that cannot be attained even by transition metal catalysis is accomplished by a P(III)/P(V) manifold.

Electrochemical, Iodine-Mediated α-CH Amination of Ketones by Umpolung of Silyl Enol Ethers

The electrochemical, oxidative Umpolung reaction of silyl enol ethers utilizing simple iodide salts for the synthesis of α-amino ketones is described. The products were isolated in excellent yields of up to 100percent, and various functionalized starting materials were accepted in an undivided electrochemical cell design. Moreover, a sensitivity assessment to ensure an improved reproducibility of the reaction and cyclic voltammetry experiments were performed to postulate a plausible reaction mechanism on their basis.