1085526-69-7Relevant articles and documents
Metal-free C8-H functionalization of quinolineN-oxides with ynamides
Hu, Weican,Zhang, Feiyang,Chen, Chen,Qi, Tianhang,Shen, Yanlong,Qian, Guoying,Rong, Zhouting
supporting information, p. 6995 - 6998 (2021/07/21)
The metal-free C8-H functionalization of quinolineN-oxides with ynamides is unveiled for the first time by the intramolecular Friedel-Crafts-type reaction of quinolyl enolonium intermediates generated from Br?nsted acid-catalyzed addition of quinolineN-ox
Regioselective iodoamination of terminal ynamides for the synthesis of α-amino-β,β-diiodo-enamides
Huang, Hai,Tang, Luning,Han, Xiaobo,He, Guangke,Xi, Yang,Zhu, Hongjun
supporting information, p. 4321 - 4324 (2016/03/22)
A mild and efficient methodology involving the I2/TBHP-mediated intermolecular iodoamination of ynamides with amines for the synthesis of α-amino-β,β-diiodo-enamides was developed. This reaction provides the first intermolecular iodoamination o
Palladium-mediated [2+1] cycloaddition of norbornene derivatives with ynamides
Clavier, Herve,Lepronier, Aymeric,Bengobesse-Mintsa, Nathalie,Gatineau, David,Pellissier, Helene,Giordano, Laurent,Tenaglia, Alphonse,Buono, Gerard
supporting information, p. 403 - 408 (2013/05/22)
An efficient palladium-catalyzed [2+1] cycloaddition between ynamides and norbornenes or norbornadienes is reported. Both phosphapalladacycles and palladium/secondary phosphine oxide catalytic systems were found to be competent for the transformation allowing the preparation of aminomethylenecyclopropanes. The reaction showed general applicability to various functionalized bicyclo[2.2.1]hept-2-enes and ynamides. A chiral phosphapalladacycle was tested to carry out this transformation in an enantioselective fashion.
