110562-21-5

Basic information

• Product Name: N-(-3-methoxy-2-aminobenzoyl)-L-prolinal dimethyl acetal
• Synonyms: N-(-3-methoxy-2-aminobenzoyl)-L-prolinal dimethyl acetal
• CAS NO: 110562-21-5
• Molecular Weight: 294.351
• Mol File: 110562-21-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(-3-methoxy-2-aminobenzoyl)-L-prolinal dimethyl acetal(CAS DataBase Reference)
• NIST Chemistry Reference: N-(-3-methoxy-2-aminobenzoyl)-L-prolinal dimethyl acetal(110562-21-5)
• EPA Substance Registry System: N-(-3-methoxy-2-aminobenzoyl)-L-prolinal dimethyl acetal(110562-21-5)

Safety Data

• Hazardous Substances Data: 110562-21-5(Hazardous Substances Data)

Upstream product

• 110562-20-4 Cbz-Pro-L-prolinal dimethyl acetal 
• 71461-30-8 (S)-2-formylpyrrolidine-1-carboxylic acid benzyl ester 
• 117082-61-8 N-(3-methoxy-2-nitrobenzoyl)-L-proline methyl ester 
• 117143-70-1 N-(3-methoxy-2-nitrobenzoyl)-L-prolinal 
• 117082-62-9 N-(3-methoxy-2-nitrobenzoyl)-L-prolinol 
• 73453-77-7 3-(4,4-dimethyloxazolin 2-yl)anisole 
• 110562-19-1 tert-butoxycarbonyl-L-prolinal dimethyl acetal 
• 69610-41-9 Boc-L-Pro-H 
• 59936-29-7 (S)-N-(tert-butoxycarbonyl)proline methyl ester 
• 69610-40-8 N-(tert-butoxycarbonyl)-L-prolinol 
• 2577-48-2 methyl (2S)-pyrrolidine carboxylate 
• 4920-80-3 3-methoxy-2-nitrobenzoic acid 
• 63478-14-8 2-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)-6-methoxyaniline 
• 117082-63-0 N-(3-methoxy-2-nitrobenzoyl)-L-prolinal dimethyl acetal 

Relevant articles and documents

New methods and reagents in organic synthesis. 92. A stereoselective synthesis of tilivalline and its analogs

Tilivalline (1a), a metabolite from Klebsiella pneumoniae var. oxytoca, and its derivatives 1 have been efficiently and stereoselectively synthesized from diphenyl phosphorazidate, the 2-oxazoline 2, the L-proline derivatives 5, and indole; the key step is a Mannich type intramolecular cyclization accompanied with completely stereoselective introduction of indole. Furthermore, 11-substituted 5H- pyrrolo[2,1-c][1,4]benzodiazepin-5-ones (16) have been also synthesized from the acetal amide 9a and various nucleophiles by the use of this new Mannich type cyclization.