110598-41-9

Basic information

• Product Name: [(E)-2-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane
• Synonyms: [(E)-2-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane
• CAS NO: 110598-41-9
• Molecular Weight: 220.387
• Mol File: 110598-41-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(E)-2-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: [(E)-2-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane(110598-41-9)
• EPA Substance Registry System: [(E)-2-(4-Methoxy-phenyl)-propenyl]-trimethyl-silane(110598-41-9)

Safety Data

• Hazardous Substances Data: 110598-41-9(Hazardous Substances Data)

Upstream product

• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 77464-22-3 2-Methyl-2-(4-methoxyphenyl)-1,3-dithiane 
• 41159-07-3 2-(4-methoxyphenyl)-2-methyl-1,3-dithiolane 
• 6224-91-5 trimethyl(prop-1-ynyl)silane 
• 696-62-8 para-iodoanisole 

Relevant articles and documents

The Effect of the Ring Size of the Dithiolato Leaving Group on the Orientation of β-Elimination in the Nickel-catalysed Alkenation of Cyclic Dithioacetals with Me3SiCH2MgCl

The product distribution (allyl- vs. vinyl-silanes) of the reactions of dithioacetals derived from alkyl aryl ketones with Me3SiCH2MgCl surprisingly depends on ring size of the cyclic dithioacetals, the five-membered ring substrates affording allylsilane as the major product while the six-membered analogues yield vinylsilanes predominantly.These results indicate that the leaving group, dithiolato moiety, may remain coordinated to the metal centre during the course of the catalytic process.