110638-25-0

Basic information

• Product Name: Aluminum, bis(2,2-dimethylpropyl)(methanaminato)-
• CAS NO: 110638-25-0
• Molecular Formula: C11H26AlN
• Molecular Weight: 199.316
• Mol File: 110638-25-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Aluminum, bis(2,2-dimethylpropyl)(methanaminato)-(CAS DataBase Reference)
• NIST Chemistry Reference: Aluminum, bis(2,2-dimethylpropyl)(methanaminato)-(110638-25-0)
• EPA Substance Registry System: Aluminum, bis(2,2-dimethylpropyl)(methanaminato)-(110638-25-0)

Safety Data

• Hazardous Substances Data: 110638-25-0(Hazardous Substances Data)

Upstream product

• 42916-36-9 tris(neopentyl)aluminium 
• 110638-22-7 trineopentylaluminum*H₂NCH₃ 

Relevant articles and documents

Synthesis and characterization of neopentylaluminum compounds

The series of neopentylaluminum compounds, Al(CH2CMe3)3, Al(CH2CMe3)2H, Al(CH2CMe3)2Br, (Me3CCH2)2AlPPh2, and (Me3CCH2)2AlN(Me)H, have been prepared by reactions typical in organoaluminum chemistry and characterized by elemental and/or group analysis, cryoscopic molecular weight measurements in benzene solution, and IR and NMR spectroscopic data. All compounds in this series, except Al(CH2CMe3)3, are associated in benzene solution. Even though the neopentyl group is considered a bulky ligand with significant eteric effects, the Lewis acidity of Al(CH2CMe3)3 has been established by the formation and characterization of adducts LiAl(CH2CMe3)4, (Me3CCH2)3Al·PPh2H, and (Me3CCH2)3Al·N(Me)H2. However, since Al(CH2CMe3)3 is monomeric in benzene solution, the factors influencing the degree of association of organoaluminum compounds are discussed. The crystalline hydride Al(CH2CMe3)2H has been prepared from Al(CH2CMe3)3 and LiAlH4. The other product was LiH rather than LiAl(CH2CMe3)H3. These observations of products are unusual in organoaluminum chemistry.