42916-36-9Relevant articles and documents
Schram, Eugene P.,Sudha, Narasimhan
, p. 213 - 216 (1991)
Group 13-derived radicals from α-diimines: Via hydro-and carboalumination reactions
Bamford, Karlee L.,Bodach, Alexander,Felderhoff, Michael,Longobardi, Lauren E.,Stephan, Douglas W.
, p. 11689 - 11696 (2020/09/09)
The mechanochemical synthesis of tertiary and secondary alanes AlR3 (R = Np 1 or Mes 2; HAlR2 R = Np 3 or Mes 4) is described. These species are reacted with several α-diimines to give a series of aluminium-derived radicals of the form [(diimine)AlR2] (6-11). EPR and several crystallographic studies are reported. These species are thought to form via hydro-or carboalumination and subsequent elimination reactions. This view is supported by the structural data for minor products C12H7(NHDipp)(NDipp)AliBu25 and C13H8(C(iBu)N(m-Xy)(NH(m-Xy)))AliBu212. In addition, the characterization of (C6F5)2B(OC(C6F5)OC12H8) indicates that such a carboboration pathway also provides access to related boron-derived radicals.
Novel trivalent organometallic compounds and methods of preparing same
-
, (2008/06/13)
In the manufacture of semiconductors it is desirable to make controlled deposits of certain phosphides or arsenides of trivalent metals such as gallium, indium and aluminum. There are provided novel neopentyl derivatives of these metals whose stability characteristics makes them ideally suited for the above purpose.