112084-43-2

Basic information

• Product Name: Benzenemethanol, a-(3,3-diethoxypropyl)-
• CAS NO: 112084-43-2
• Molecular Formula: C14H22O3
• Molecular Weight: 238.327
• Mol File: 112084-43-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(3,3-diethoxypropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(3,3-diethoxypropyl)-(112084-43-2)
• EPA Substance Registry System: Benzenemethanol, a-(3,3-diethoxypropyl)-(112084-43-2)

Safety Data

• Hazardous Substances Data: 112084-43-2(Hazardous Substances Data)

Upstream product

• 35573-93-4 3-chloro-1,1-diethoxy-propane 
• 100-52-7 benzaldehyde 

Downstream Products

• 1258208-47-7 (2S,5R)-2-ethoxy-5-phenyltetrahydrofuran 
• 1258208-38-6 (S)-4,4-diethoxy-1-phenylbutan-1-ol 
• 65989-89-1 2-ethoxy-5-phenyltetrahydrofuran 

Relevant articles and documents

Kinetic resolution of homoaldols via catalytic asymmetric transacetalization

The highly enantioselective kinetic resolution of homoaldols via a transacetalization reaction has been achieved. A novel phosphoric acid, STRIP, based on a spirocyclic 1,1′-spirobiindane backbone was designed and identified as a superior catalyst for this transformation. Remarkably, both secondary and tertiary homoaldols gave equally excellent results.

3,3-Diethoxypropyl-lithium: A Masked Lithium Propanal Homoenolate

3,3-Diethoxypropyl-lithium is prepared by lithiation of the corresponding chlorinated precursor with lithium naphthalenide at - 78 deg C; the reaction of this masked propanal homoenolate with different electrophilic reagents leads to the corresponding mono- and bi-functionalized compounds.