112297-82-2

Basic information

• Product Name: l-menthyl 2-methyl-2-(trimethylsilyl)-4-phenylbutyrate
• Synonyms: l-menthyl 2-methyl-2-(trimethylsilyl)-4-phenylbutyrate
• CAS NO: 112297-82-2
• Molecular Weight: 388.666
• Mol File: 112297-82-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: l-menthyl 2-methyl-2-(trimethylsilyl)-4-phenylbutyrate(CAS DataBase Reference)
• NIST Chemistry Reference: l-menthyl 2-methyl-2-(trimethylsilyl)-4-phenylbutyrate(112297-82-2)
• EPA Substance Registry System: l-menthyl 2-methyl-2-(trimethylsilyl)-4-phenylbutyrate(112297-82-2)

Safety Data

• Hazardous Substances Data: 112297-82-2(Hazardous Substances Data)

Upstream product

• 2623-23-6 L-menthyl acetate 
• 112297-88-8 l-menthyl (trimethylsilyl)acetate 
• 29066-36-2 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl propionate 
• 103-63-9 1-phenyl-2-bromoethane 
• 74-88-4 methyl iodide 
• 119244-62-1 l-menthyl 2-(trimethylsilyl)-4-phenylbutyrate 

Downstream Products

• 83972-44-5 (R)-(+)-1-phenyl-3-(trimethylsilyl)butane 
• 83972-44-5 1-phenyl-3-(trimethylsilyl)butane 
• 112297-91-3 (R)-(+)-1,4-diphenyl-2-methyl-2-(trimethylsilyl)-1-butanone 
• 112297-95-7 Trimethyl-((R)-1-methyl-3-phenyl-propyl)-silane 
• 119244-69-8 (R)-(-)-2-methyl-2-(trimethylsilyl)-4-phenylbutanol 

Relevant articles and documents

Cleavage of Carbon-Carbon Bonds with High Stereochemical Control. 6. Asymmetric Synthesis of Chiral C-Centered Organosilanes by Haller-Bauer Cleavage of Optically Active, Nonenolizable α-Silyl Phenyl Ketones

Sequential alkylation and methylation of l-menthyl ester 10 provides diastereomeric mixtures in which 12 is slighthly enhanced over 13.Conversely, C-silation and alkylation of propionate ester 11 delivers 13 in excess.In either cause, a single chromatogra