112639-16-4

Basic information

• Product Name: Benzene, 2-iodo-1,3-dimethoxy-5-pentyl-
• CAS NO: 112639-16-4
• Molecular Formula: C13H19IO2
• Molecular Weight: 334.197
• Mol File: 112639-16-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 2-iodo-1,3-dimethoxy-5-pentyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 2-iodo-1,3-dimethoxy-5-pentyl-(112639-16-4)
• EPA Substance Registry System: Benzene, 2-iodo-1,3-dimethoxy-5-pentyl-(112639-16-4)

Safety Data

• Hazardous Substances Data: 112639-16-4(Hazardous Substances Data)

Upstream product

• 112639-12-0 1,3-dihydroxy-2-iodo-5-pentylbenzene 
• 74-88-4 methyl iodide 

Downstream Products

• 29106-16-9 1,3-bis(methoxy)cannabigerol 
• 83036-53-7 1,3-Dimethoxy-2-(3-methyl-but-2-enyl)-5-pentyl-benzene 
• 1309372-75-5 2-(2,6-dimethoxy-4-pentylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 33029-18-4 Δ⁹-tetrahydrocannabinol 
• 247227-98-1 (1S,2S)-2',6'-dimethoxy-5-methyl-4'-pentyl-2-(prop-1-en-2-yl)-1,2,3,4-tetrahydro-1,1'-biphenyl 

Relevant articles and documents

Short and Divergent Total Synthesis of (+)-Machaeriol B, (+)-Machaeriol D, (+)-Δ8-THC, and Analogues

Short and highly efficient stereoselective syntheses provide machaeriols and cannabinoids in a divergent approach starting from a common precursor, commercially available (S)-perillic acid. Key features of the novel strategy are a stereospecific palladium-catalyzed decarboxylative arylation and a one-pot sequence comprising a stereoselective hydroboration followed by oxidation or reduction of the corresponding intermediary boranes. The divergent approach is convincingly demonstrated by the five-step syntheses of (+)-machaeriol B, (+)-machaeriol D, and related analogues, and the four-step synthesis of (+)-Δ8-THC and an analogue.

Halogenation of Phenols and Phenyl Ethers with Potassium Halides in the Presence of 18-Crown-6 on Oxidation with m-Chloroperbenzoic Acid

Several types of phenyl ethers have been monobrominated in the ring in good yields with potassium bromide in the presence of 18-crown-6 on oxidation with m-chloroperbenzoic acid.Monoiodination takes place with both phenyl ethers and free phenols when potassium iodide is employed.