247227-98-1

Basic information

• Product Name: Benzene, 1,3-dimethoxy-2-[(1S,6S)-3-methyl-6-(1-methylethenyl)-2-cyclohexen-1- yl]-5-pentyl-
• CAS NO: 247227-98-1
• Molecular Formula: C23H34O2
• Molecular Weight: 342.522
• Mol File: 247227-98-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,3-dimethoxy-2-[(1S,6S)-3-methyl-6-(1-methylethenyl)-2-cyclohexen-1- yl]-5-pentyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,3-dimethoxy-2-[(1S,6S)-3-methyl-6-(1-methylethenyl)-2-cyclohexen-1- yl]-5-pentyl-(247227-98-1)
• EPA Substance Registry System: Benzene, 1,3-dimethoxy-2-[(1S,6S)-3-methyl-6-(1-methylethenyl)-2-cyclohexen-1- yl]-5-pentyl-(247227-98-1)

Safety Data

• Hazardous Substances Data: 247227-98-1(Hazardous Substances Data)

Upstream product

• 112639-16-4 2-iodo-1,3-dimethoxy-5-pentylbenzene 
• 67-56-1 methanol 
• 74219-29-7 (1'S,2'S)-5'-methyl-4-pentyl-2'-(prop-1-en-2-yl)-1',2',3',4'-tetrahydro-[1,1'-biphenyl]-2,6-diol 

Downstream Products

• 847949-27-3 2-((1S,6S)-3-Bromomethyl-6-isopropenyl-cyclohex-2-enyl)-1,3-dimethoxy-5-pentyl-benzene 
• 847949-29-5 [(3S,4S)-3-(2,6-Dimethoxy-4-pentyl-phenyl)-4-isopropenyl-cyclohex-1-enyl]-methanol 
• 847949-28-4 Acetic acid (3S,4S)-3-(2,6-dimethoxy-4-pentyl-phenyl)-4-isopropenyl-cyclohex-1-enylmethyl ester 
• 847949-33-1 Acetic acid 3-acetoxy-2-((1S,6S)-3-formyl-6-isopropenyl-cyclohex-2-enyl)-5-pentyl-phenyl ester 
• 847949-32-0 Acetic acid 3-acetoxy-2-((1S,6S)-3-bromomethyl-6-isopropenyl-cyclohex-2-enyl)-5-pentyl-phenyl ester 
• 847949-34-2 (3S,4S)-3-(2,6-Diacetoxy-4-pentyl-phenyl)-4-isopropenyl-cyclohex-1-enecarboxylic acid 
• 33029-18-4 Δ⁹-tetrahydrocannabinol 
• 847949-24-0 (1R,4S,5S,6S)-5-(2,6-Dimethoxy-4-pentyl-phenyl)-4-isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]heptane 

Relevant articles and documents

Short and Divergent Total Synthesis of (+)-Machaeriol B, (+)-Machaeriol D, (+)-Δ8-THC, and Analogues

Short and highly efficient stereoselective syntheses provide machaeriols and cannabinoids in a divergent approach starting from a common precursor, commercially available (S)-perillic acid. Key features of the novel strategy are a stereospecific palladium-catalyzed decarboxylative arylation and a one-pot sequence comprising a stereoselective hydroboration followed by oxidation or reduction of the corresponding intermediary boranes. The divergent approach is convincingly demonstrated by the five-step syntheses of (+)-machaeriol B, (+)-machaeriol D, and related analogues, and the four-step synthesis of (+)-Δ8-THC and an analogue.