1128-57-0Relevant articles and documents
Nucleophilic deoxyfluorination of catechols
Nemoto, Hiroyuki,Nishiyama, Tsuyoshi,Akai, Shuji
supporting information; experimental part, p. 2714 - 2717 (2011/06/28)
Nucleophilic deoxyfluorinaiton of one of the two hydroxyl groups of catechols has been developed via the Umpolung concept. This method was successively applied to naturally occurring catechols, such as catechins and dopamine, to produce novel fluorinated
Molecular actuator: Redox-controlled clam-like motion in a bichromophoric electron donor
Chebny, Vincent J.,Shukla, Ruchi,Lindeman, Sergey V.,Rathore, Rajendra
supporting information; experimental part, p. 1939 - 1942 (2009/09/25)
The one-electron oxidation of tetramethoxydibenzobicyclo[4.4.1]undecane (4) prompts it to undergo a clam-like electromechanical actuation into a cofacially -stacked conformer as established by (i) electrochemical analysis, (ii) by the observation of the i
Chemistry of 2-Methoxy-2,5-cyclohexadienones. I. Photochemistry of 2-Methoxy-4,4-dimethyl-2,5-cyclohexadienone
Matoba, Katsuhide,Karibe, Norio,Yamazaki, Takao
, p. 3906 - 3911 (2007/10/02)
The title compound, 2-methoxy-4,4-dimethyl-2,5-cyclohexadienone (V), was prepared from 2-methoxy-4,4-dimethyl-2-cyclohexenone (VIa).A methanolic solution of V was irradiated with a 200 W mercury lamp at -3 deg C to give 2,2-dimethoxy-6,6-dimethylbicyclo3