112836-09-6

Basic information

• Product Name: (1R,2R,4R)-bicyclo[2.2.1]hept-5-en-2-yl acetate
• Synonyms: (1R,2R,4R)-bicyclo[2.2.1]hept-5-en-2-yl acetate
• CAS NO: 112836-09-6
• Molecular Weight: 152.193
• Mol File: 112836-09-6.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: (1R,2R,4R)-bicyclo[2.2.1]hept-5-en-2-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,4R)-bicyclo[2.2.1]hept-5-en-2-yl acetate(112836-09-6)
• EPA Substance Registry System: (1R,2R,4R)-bicyclo[2.2.1]hept-5-en-2-yl acetate(112836-09-6)

Safety Data

• Hazardous Substances Data: 112836-09-6(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 694-97-3 endo-5-norbornen-2-ol 
• 2890-95-1 5-norbornenyl-2-acetate 
• 63318-61-6 α-Aethoxyacrylsaeuremethylester 
• 292638-85-8 acrylic acid methyl ester 
• 72150-05-1 Essigsaeure<6endo-tosyloxy-2endo-norbornyl>ester 
• 72150-05-1 Essigsaeure-<6exo-tosyloxy-2endo-norbornyl>ester 
• 694-98-4 norborn-5-en-2-one 
• 279-19-6 nortricyclane 
• 64-19-7 acetic acid 
• 542-92-7 cyclopenta-1,3-diene 

Downstream Products

• 694-97-3 (1S,2S,4S)-bicyclo[2.2.1]hept-5-en-2-ol 
• 154278-40-7 (1S,2S,4S)-bicyclo[2.2.1]hept-5-en-2-yl acetate 
• 106928-44-3 (1R,2R,4R)-endo-bicyclo[2.2.1]hept-5-en-2-ol 
• 29583-33-3 (+/-)-endo-norborneol acetate 
• 78365-85-2 5-endo-Methyl-2-norbornanon-tosylhydrazon 
• 78365-87-4 6-endo-Methyl-2-norbornanon-tosylhydrazon 
• 162307-06-4 5-exo,6-exo-difluorobicyclo<2.2.1>heptan-2-yl acetate 
• 34640-76-1 exo-2-norbornyl acetate 
• 100871-13-4 (+/-)-3,5-dinitro-benzoic acid-[2endo]norbornyl ester 
• 61242-45-3 (+/-)-phthalic acid mono-[2endo]norbornyl ester 
• 497-36-9 (+/-)-endo-2-norborneol 
• 694-98-4 norborn-5-en-2-one 
• 497-38-1 Norbornan-2-on 
• 497-38-1 (1S,4R)-bicyclo[2.2.1]heptan-2-one 

Relevant articles and documents

(Meth) acrylate derivative, polymer and photoresist composition having lactone structure, and method for forming pattern by using it

There are here disclosed a photoresist material for lithography using a light of 220 nm or less which comprises at least a polymer represented by the following formula (2) and a photo-acid generator for generating an acid by exposure: wherein R1, R2, R3 and R5 are each a hydrogen atom or a methyl group; R4 is an acid-labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has an acid labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group, or a hydrocarbon group having 3 to 13 carbon atoms, which has an epoxy group; R6 is a hydrogen atom, a hydrocarbon group having 1 to 12 carbon atoms, or an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group; x, y and z are optional values which meet x+y+z=1, 0a weight-average molecular weight of the polymer is in the range of 2000 to 200000, and a resin having a (meth)acrylate unit of an alicyclic lactone structure represented by the formula (3): wherein R8 is a hydrogen atom or a methyl group, and R9 is a hydrocarbon group of 7 to 16 carbon atoms having an alicyclic lactone structure.

Ring-opening metathesis - Cross-metathesis reactions (ROM-CM) of substituted norbornadienes and norbornenes

Ring-opening metathesis - cross-metathesis reactions (ROM-CM) of substituted norbornadienes and norbornenes were investigated. The reactions with symmetrical 2,3-disubstituted norbornadienes were found to be highly chemoselective, with the ROM reactions occurring only on the less substituted or less sterically hindered double bonds regardless of the electronic nature of the substituents, giving highly substituted cyclopentenes in moderate to good yields. This study provides an efficient method for the stereoselective synthesis of highly substituted cyclopentenoids. Long-range electronic effect of a remote substituent on unsymmetrical norbornenes in the ROM-CM reactions was also investigated. Low levels of regioselectivities were observed (50:50 to 69:31) with various remote substituents on the norbornenes.

Effect of supramolecular inclusion on the selectivity of 3-nortricyclanylidene

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