112897-09-3

Basic information

• Product Name: 5-Hexen-3-ol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (R)-
• CAS NO: 112897-09-3
• Molecular Formula: C22H30O2Si
• Molecular Weight: 354.565
• Mol File: 112897-09-3.mol
• Article Data: 34

Chemical Properties

• CAS DataBase Reference: 5-Hexen-3-ol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexen-3-ol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (R)-(112897-09-3)
• EPA Substance Registry System: 5-Hexen-3-ol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (R)-(112897-09-3)

Safety Data

• Hazardous Substances Data: 112897-09-3(Hazardous Substances Data)

Upstream product

• 24850-33-7 allyltributylstanane 
• 112897-03-7 3-(tert-butyldiphenylsilyloxy)-1-propanal 
• 447440-43-9 (4S,5S)-2-allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine 
• 866455-76-7 (3R)-5-hexene-1,3-diol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 85116-38-7 (+)-diisopinocampheylallylborane 
• 1774-47-6 trimethylsulfoxonium iodide 
• 125975-53-3 tert-butyl [2-[(2R)-oxiran-2-yl]ethoxy]diphenylsilane 
• 1826-67-1 vinyl magnesium bromide 
• 2622-05-1 allylmagnesium bromide 
• 604774-80-3 (1R,2S,3R,4S)-2,3-O-[allylboryl]-2-phenyl-1,7,7-trimethylbornanediol 
• 77078-87-6 (1R,2S,3R,4S)-2,3-O-(allylboryl)-2-phenyl-1,7,7-trimethylbornanediol 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 116996-55-5 4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-iodomethyl-[1,3]dioxan-2-one 
• 116996-55-5 (3S,5S)-5-(iodomethyl)-3-[2-(t-butyldiphenylsilyloxy)ethyl]-2,6-dioxacyclohexanone 
• 714966-47-9 (2E,5S)-7-(t-butyldiphenylsilyloxy)-5-hydroxyhept-2-enoic acid methyl ester 
• 866455-77-8 6-(tert-butyl-diphenyl-silanyloxy)-4-hydroxy-hexan-2-one 
• 851592-85-3 (5-methyl-[1,3]dioxan-4-ylidene)-acetic acid 1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyl ester 
• 851592-80-8 (2S,3S,6R)-6-Allyl-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-hydroxymethyl-3-methyl-tetrahydro-pyran-4-one 
• 851592-87-5 (5-methyl-6H-[1,3]dioxin-4-yl)-acetic acid 1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyl ester 
• 851592-79-5 acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester 
• 851770-87-1 (5-methyl-[1,3]dioxan-4-yl)-phenylsulfanyl-acetic acid 1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyl ester 
• 865352-94-9 benzenesulfinyl-(5-methyl-[1,3]dioxan-4-yl)-acetic acid 1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyl ester 
• 851770-88-2 3-hydroxy-5-methoxymethoxy-4-methyl-2-phenylsulfanyl-pentanoic acid 1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyl ester 
• 1011481-93-8 tert-butyl(3-methoxyhex-5-enyloxy)diphenylsilane 
• 1221563-79-6 C₂₄H₃₄O₃Si 
• 1372713-56-8 (6S)-6-[2-(tert-butyldiphenylsiloxy)ethyl]-5,6-dihydro-2H-pyran-2-one 

Relevant articles and documents

A Method for the Stereoselective Construction of the Hemiaminal Center in Zampanolides

We have developed a new method for the stereoselective establishment of the N-acyl hemiaminal moiety in zampanolide-type structures that involves the reaction of (Z,E)-sorbamide (3) with BINAL-H and subsequent amide transfer from a putative aluminum carbo

Remarkable Influence of Cobalt Catalysis on Epoxide Ring-Opening with Sulfoxonium Ylides

Cobalt demonstrates a remarkable ability to catalytically divert the course of epoxide to oxetane ring expansion via reaction with a sulfoxonium ylide. An expanded survey of transition-metal catalysts has confirmed that cobalt salts uniquely instead deliv

Divergent reactivity via cobalt catalysis: An epoxide olefination

Cobalt salts exert an unexpected and profound influence on the reactivity of epoxides with dimethylsulfoxonium methylide. In the presence of a cobalt catalyst, conditions for epoxide to an oxetane ring expansion instead deliver homoallylic alcohol products, corresponding to a two-carbon epoxide homologation/ring-opening tandem process. The observed reactivity change appears to be specifically due to cobalt salts and is broadly applicable to a variety of epoxides, retaining the initial stereochemistry. This transformation also provides operationally simple access to enantiopure homoallylic alcohols from chiral epoxides without use of organometallic reagents. Tandem epoxidation-homologation of aldehydes in a single step is also demonstrated.