77078-87-6

Basic information

• Product Name: (1R,2S,3R,4S)-2,3-O-(allylboryl)-2-phenyl-1,7,7-trimethylbornanediol
• Synonyms: (1R,2S,3R,4S)-2,3-O-(allylboryl)-2-phenyl-1,7,7-trimethylbornanediol
• CAS NO: 77078-87-6
• Molecular Weight: 296.217
• Mol File: 77078-87-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S,3R,4S)-2,3-O-(allylboryl)-2-phenyl-1,7,7-trimethylbornanediol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,3R,4S)-2,3-O-(allylboryl)-2-phenyl-1,7,7-trimethylbornanediol(77078-87-6)
• EPA Substance Registry System: (1R,2S,3R,4S)-2,3-O-(allylboryl)-2-phenyl-1,7,7-trimethylbornanediol(77078-87-6)

Safety Data

• Hazardous Substances Data: 77078-87-6(Hazardous Substances Data)

Upstream product

• 31503-17-0 (-)-(1R,2R,3R,4S)-1,7,7-trimethyl-2-phenyl-bicyclo[2.2.1]heptane-2,3-diol 
• 106-95-6 allyl bromide 

Downstream Products

• 77118-87-7 (S)-1-Phenyl-3-buten-1-ol 
• 85551-57-1 (R)-1-Phenylbut-3-en-1-ol 
• 112897-09-3 (3R)-1-(tert-butyldiphenylsilyloxy)hex-5-en-3-ol 
• 112897-09-3 (3S)-1-{[t-butyl(diphenyl)silyl]oxy}hex-5-en-3-ol 
• 127793-64-0 (R)-1-O-(tert-butyldiphenylsilyl)-4-penten-1,2-diol 
• 127793-64-0 (2S)-1-{[tert-butyl(diphenyl)silyl]oxy}pent-4-en-2-ol 
• 58931-16-1 (R)-1-benzyloxypent-4-en-2-ol 
• 88981-35-5 (2S)-1-(benzyloxy)pent-4-en-2-ol 
• 60340-28-5 (S)-1-phenyl-5-hexen-3-ol 

Relevant articles and documents

Scandium-catalyzed allylboration of aldehydes as a practical method for highly diastereo- and enantioselective construction of homoallylic alcohols

A general approach for the allylation of aldehydes using stable, air-tolerant camphor-based chiral allylboronates under Sc(OTf)3 catalysis is described. This practical methodology provides both syn and anti propionate units and other homoallylic alcohols with very high levels of diastereo- and enantioselectivity for several substrates, including functionalized aliphatic aldehydes useful toward the elaboration of complex natural products. Copyright