113094-18-1

Basic information

• Product Name: 3-(m-chlorophenyl)carbamoylaza-4-oxotetracyclo<4.2.1.0>nonane
• Synonyms: 3-(m-chlorophenyl)carbamoylaza-4-oxotetracyclo<4.2.1.0>nonane
• CAS NO: 113094-18-1
• Molecular Weight: 290.749
• Mol File: 113094-18-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(m-chlorophenyl)carbamoylaza-4-oxotetracyclo<4.2.1.0>nonane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(m-chlorophenyl)carbamoylaza-4-oxotetracyclo<4.2.1.0>nonane(113094-18-1)
• EPA Substance Registry System: 3-(m-chlorophenyl)carbamoylaza-4-oxotetracyclo<4.2.1.0>nonane(113094-18-1)

Safety Data

• Hazardous Substances Data: 113094-18-1(Hazardous Substances Data)

Upstream product

• 7486-95-5 exo-3-azatricyclo<4.2.1.0^2,5>nonan-4-one 
• 2909-38-8 m-chlorophenyl isocyanate 

Relevant articles and documents

STEREOCHEMICAL STUDIES 107; SATURATED HETEROCYCLES 111; PREPARATION OF URACILS VIA CYCLOREVERSION OF NORBORNENE-FUSED PYRIMIDINEDIONES

From diexo-norbornane- and norbornene-azetidinones 5 and 6 with aryl isocyanates, N-arylcarbamoyl-substituted β-lactams (9 and 10) were prepared.The structures of the compounds were elucidated by IR, NMR spectroscopy and X-ray analysis, in comparison with saturated methylene-bridged quinazoline-2,4-diones (7a-b) prepared from norbornane-diexo-β-amino acid (1) with isocyanates and PPA.When heated with PPA, compounds 9 can be isomerized to 7.For preparation of the unsaturated compounds 8, the amino acid 2 was converted into the acid amides (13) and cyclized with 1,1'-carbonyl-diimidazole to tricyclic quinazoline-2,4-dione (8a-e), which decompose when heated, splitting off cyclopentadiene to yield 3-substituted uracils (14).