113322-93-3

Basic information

• Product Name: (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)
• Synonyms: (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)
• CAS NO: 113322-93-3
• Molecular Weight: 839.817
• Mol File: 113322-93-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)(113322-93-3)
• EPA Substance Registry System: (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)(113322-93-3)

Safety Data

• Hazardous Substances Data: 113322-93-3(Hazardous Substances Data)

Upstream product

• 32993-05-8 chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) 
• 1493-13-6 trifluorormethanesulfonic acid 
• 2923-28-6 silver trifluoromethanesulfonate 
• 603-35-0 triphenylphosphine 
• 624-49-7 dimethylfumarate 

Downstream Products

• 122070-60-4 {CpRu(PPh3)2}2(μ-SH)(OTf) 
• 122070-52-4 C₅H₅Ru(P(C₆H₅)3)2SH₂⁽¹⁺⁾*OSO₂CF₃^(1-)={C₅H₅Ru(P(C₆H₅)3)2SH₂}OSO₂CF₃ 
• 34692-10-9 [ruthenium(II)I(η5-C5H5)(P(C6H5)3)2] 
• 113322-95-5 {(C₅H₅)Ru(P(C₆H₅)3)2(SC₂H₄)}⁽¹⁺⁾*CF₃SO₃^(1-)*0.5CH₂Cl₂={(C₅H₅)Ru(P(C₆H₅)3)2(SC₂H₄)}(OSO₂CF₃)*0.5CH₂Cl₂ 

Relevant articles and documents

Remarkable activity of the isomerization catalyst [RuCp(PPh 3)2](OTs) in O-allylation of phenol with allyl alcohol

It was surprisingly found that the highly active allyl alcohol redox isomerization catalyst [RuCp(PPh3)2](OTs) upon addition of a catalytic amount of a strong acid can change its catalytic action fully to the selective O-allylation of phenols with allyl alcohol. High turnover numbers (75,000 based on phenol; 200,000 based on allyl alcohol) are reached, and the catalyst is very stable in the presence of substrate. Addition of triphenylphosphine to the reaction mixture does not lead to further stabilization of the catalyst; instead, the free phosphine is rapidly allylated, thereby consuming the acid, which deactivates the catalytic system for allylation reactions. This catalyst with monodentate phosphine ligands is superior in both activity and selectivity to similar catalysts with bidentate phosphine ligands. Apart from phenols, also thiophenol can be efficiently allylated to form allyl phenyl sulfide.