113416-21-0

Basic information

• Product Name: 2-Butenoic acid, 4-oxo-4-phenyl-2-(phenylamino)-, methyl ester
• CAS NO: 113416-21-0
• Molecular Formula: C17H15NO3
• Molecular Weight: 281.311
• Mol File: 113416-21-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Butenoic acid, 4-oxo-4-phenyl-2-(phenylamino)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 4-oxo-4-phenyl-2-(phenylamino)-, methyl ester(113416-21-0)
• EPA Substance Registry System: 2-Butenoic acid, 4-oxo-4-phenyl-2-(phenylamino)-, methyl ester(113416-21-0)

Safety Data

• Hazardous Substances Data: 113416-21-0(Hazardous Substances Data)

Upstream product

• 93-58-3 benzoic acid methyl ester 
• 62-53-3 aniline 
• 67-64-1 acetone 
• 20577-73-5 methyl 4-phenyl-2,4-dioxobutanoate 
• 41167-58-2 2-hydroxy-4-oxo-4-phenyl-but-2-enoic acid methyl ester 
• 41158-32-1 methyl 4-oxo-4-phenylbut-2-ynoate 

Downstream Products

• 1137860-78-6 methyl 4,9-dibenzoyl-3-hydroxy-1-(2-hydroxyphenyl)-2,6-dioxo-7-phenyl-1,7-diazaspiro[4.4]nona-3,8-diene-8-carboxylate 
• 15431-98-8 N-Phenyl-benzoylbrenztraubensaeureamid 
• 113416-32-3 4-benzoyl-5-methoxycarbonyl-1-phenyl-2,3-dihydropyrrole-2,3-dione 
• 65387-40-8 α-phenylaminobenzoylacrylic acid 
• 113416-61-8 2-hydroxy-4-oxo-4-phenylbut-2-enoic acid 
• 85635-61-6 (Z)-2-hydroxy-4-oxo-N,4-diphenylbut-2-enamide 
• 39847-99-9 (Z)-methyl 2-hydroxy-4-oxo-4-phenylbut-2-enoate 

Relevant articles and documents

Synthesis of: Meta-substituted anilines via a three-component reaction of acetone, amines, and 1,3-diketones

A facile method for the synthesis of meta-substituted arylamines from acyclic precursors was developed. This method is based on three-component cyclo-condensation/aromatization of in situ generated imines of acetone with 1,3-diketones either under conventional heating or under microwave irradiation. The utility of this methodology is illustrated by the possibility of a gram scale synthesis of various anilines from readily available reagents.

FIVE-MEMBERED 2,3-DIOXOHETEROCYCLES. V. SYNTHESIS OF 1-ARYL-4-AROYL-5-METHOXYCARBONYL-2,3-DIHYDRO-2,3-PYRROLEDIONES AND THEIR REACTIONS WITH WATER AND ALCOHOLS

1-Aryl-4-aroyl-5-methoxycarbonyl-2,3-dihydro-2,3-pyrrolediones were obtained from oxalyl chloride and methyl 4-aryl-2-arylamino-4-oxo-2-butenoates.They add water and alcohols reversibly with the formation of substituted 3,5-dihydroxy- and 5-alkoxy-3-hydro