1142-24-1Relevant articles and documents
Reductive amination of aldehydes and ketones catalyzed by deep eutectic solvent using sodium borohydride as a reducing agent
Saberi, Dariush,Akbari, Jafar,Mahdudi, Samaneh,Heydari, Akbar
, p. 208 - 210 (2014)
Different derivatives of aldehydes/ketones were subjected under reductive amination reaction in the presence of ChCl/Urea as a green and biocompatible catalyst. Sodium borohydride was used as a reducing agent. Secondary amines were achieved with high selectivities and yields.
Rich Coordination Chemistry of π-Acceptor Dibenzoarsole Ligands
Gupta, Arvind Kumar,Akkarasamiyo, Sunisa,Orthaber, Andreas
, p. 4504 - 4511 (2017)
A series of dibenzoarsole (also known as 9-arsafluorene) derivatives have been prepared, and their coordination chemistry has been investigated. The different ligand topology and the arsenic substituents govern the reactivity of the ligands. We report various crystal structures of palladium and platinum complexes derived from this family of ligands. The biphenyl backbone of the bridged bidentate ligands allows very flexible coordination. We have also studied the application of an allylic Pd complex in nucleophilic substitution reactions, revealing that the benzoarsole substituent is susceptible to metal insertion.
PH-Mediated Selective Synthesis of N-Allylic Alkylation or N-Alkylation Amines with Allylic Alcohols via an Iridium Catalyst in Water
Luo, Nianhua,Zhong, Yuhong,Shui, Hongling,Luo, Renshi
supporting information, p. 15509 - 15521 (2021/11/01)
Amination of allylic alcohols is an effective approach in the facile synthesis of N-allylic alkylation or N-alkylation amines. Recently, a series of catalysts were devised to push forward this transformation. However, current synthetic methods are typical
Sulfated polyborate: A dual catalyst for the reductive amination of aldehydes and ketones by NaBH4
Ganwir, Prerna,Chaturbhuj, Ganesh
, (2021/05/19)
An efficient, quick, and environment-friendly one-pot reductive amination of aldehydes or ketones was developed. In ethanol at 70 °C, a imination catalyzed by sulfated polyborate and further reduced by sodium borohydride yields various amines. The present method has many significant benefits, including a shorter reaction time, excellent yields, and a hassle-free, straightforward experimental process. The reaction has a wide range of applications due to its flexibility, including secondary amine for reductive amination.