5848-59-9

Basic information

• Product Name: N-cinnamyl-4-methyl-N-phenylbenzenesulfonamide
• CAS NO: 5848-59-9
• Molecular Weight: 363.48
• Mol File: 5848-59-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N-cinnamyl-4-methyl-N-phenylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-cinnamyl-4-methyl-N-phenylbenzenesulfonamide(5848-59-9)
• EPA Substance Registry System: N-cinnamyl-4-methyl-N-phenylbenzenesulfonamide(5848-59-9)

Safety Data

• Hazardous Substances Data: 5848-59-9(Hazardous Substances Data)

Upstream product

• 1142-24-1 N-cinnamylbenzenamine 
• 98-59-9 p-toluenesulfonyl chloride 
• 100-52-7 benzaldehyde 
• 103-36-6 ethyl 3-phenyl-2-propenoate 
• 104-54-1 3-Phenylpropenol 
• 68-34-8 phenyl toluenesulfonamide 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 62-53-3 aniline 
• 104-55-2 3-phenyl-propenal 
• 673-32-5 1-Phenylprop-1-yne 
• 5044-52-0 vinyltriphenylphosphonium bromide 

Downstream Products

• 10174-54-6 4-phenyl-1-tosyl-1,2-dihydroquinoline 
• 1167445-42-2 C₂₈H₂₅NO₂SSe 
• 132704-08-6 2-(Chloro-phenyl-methyl)-4-(toluene-4-sulfonyl)-3,4-dihydro-2H-benzo[1,4]thiazine 

Relevant articles and documents

Halogen Bond Catalyzed Bromocarbocyclization

A halogen bond catalyzed bromo-carbocyclization of N-cinnamyl sulfonamides and O-cinnamyl phenyl ethers has been developed. N-methyl 4-iodopyridinium triflate is used as the halogen-bonding organocatalyst and the reaction is highly chemoselective. This report represents the first proof-of-concept for halogen-bonding organocatalyst-promoted electrophilic halogenation. Mechanistic study suggests the autocatalytic nature of this reaction.

Allylic activation across an Ir-Sn heterobimetallic catalyst: Nucleophilic substitution and disproportionation of allylic alcohol

A nucleophilic substitution of allylic alcohols with carbon (arene, heteroarene, allyltrimethylsilane, and 1,3-dicarbonyl compound), sulfur (thiol), oxygen (alcohol), and nitrogen (sulfonamide) nucleophiles has been demonstrated using an in house developed [Ir(COD)(SnCl3)l(μ-Cl)]2 heterobimetallic catalyst in 1,2-dichloroethane to afford the corresponding allylic products in moderate to excellent yields. In 4-hydroxycoumarin, allylation occurs at the 3-position. The diaryl-substituted allylic alcohols undergo disproportionation in presence of the heterobimetallic catalyst to provide the corresponding alkenes and chalcones. An electrophilic mechanism is proposed from Hammett correlation study.

Die Reaktion von γ-substituierten N-Allyl-anilinen mit Schwefeldichlorid - eine Synthese von 2,3-Dihydro-1,4-benzothiazinen

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