114303-65-0

Basic information

• Product Name: Benzene, 4-bromo-1-methoxy-2-(2-propenyl)-
• CAS NO: 114303-65-0
• Molecular Formula: C10H11BrO
• Molecular Weight: 227.101
• Mol File: 114303-65-0.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, 4-bromo-1-methoxy-2-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 4-bromo-1-methoxy-2-(2-propenyl)-(114303-65-0)
• EPA Substance Registry System: Benzene, 4-bromo-1-methoxy-2-(2-propenyl)-(114303-65-0)

Safety Data

• Hazardous Substances Data: 114303-65-0(Hazardous Substances Data)

Upstream product

• 182056-39-9 2-bromo-4-iodo-1-methoxybenzene 
• 106-95-6 allyl bromide 
• 106-41-2 4-bromo-phenol 
• 1465765-08-5 C₁₇H₁₅BrO₃ 
• 25244-30-8 4-(allyloxy)bromobenzene 
• 3536-96-7 vinylmagnesium chloride 
• 184970-28-3 4-bromo-2-(bromomethyl)-1-methoxybenzene 
• 80866-82-6 5-bromo-2-methoxy-benzyl alcohol 
• 607-99-8 2,4,6-tribromoanisole 
• 13997-74-5 2-allyl-4-bromophenol 
• 74-88-4 methyl iodide 
• 21702-84-1 2,4-dibromoanisole 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 905562-52-9 3-(3-bromo-6-methoxyphenyl)propane-1,2-diol 
• 68592-15-4 methylhonokiol 
• 1378871-34-1 4-methoxy-3-allyl-1-phenylboronic acid 
• 905562-85-8 3-allyl-4-methoxy-N,N-dimethylbenzamide 
• 67483-48-1 3-allyl-4-methoxybenzaldehyde 
• 261769-32-8 6-(3-allyl-4-methoxy-phenyl)-6-methoxymethoxy-hexan-1-ol 
• 261769-33-9 6-(3-allyl-4-methoxy-phenyl)-6-methoxymethoxy-hexanal 
• 261769-31-7 1-(3-allyl-4-methoxy-phenyl)-6-(tert-butyl-dimethyl-silanyloxy)-hexan-1-ol 

Relevant articles and documents

Regioselective Bromine/Magnesium Exchange for the Selective Functionalization of Polyhalogenated Arenes and Heterocycles

Using the bimetallic combination sBu2Mg?2 LiOR (R=2-ethylhexyl) in toluene enables efficient and regioselective Br/Mg exchanges with various dibromo-arenes and -heteroarenes under mild reaction conditions and provides bromo-substituted magnesiu

Selective formation of non-conjugated olefins by samarium(II)-mediated elimination/isomerization of allylic benzoates

Aromatic allylic benzoates can be selectively transformed to the corresponding benzoate eliminated olefin by the action of samarium diiodide. Depending on the substrate and the elimination conditions, high selectivity for the non-conjugated alkene product

Expedient synthesis of 4-O-methylhonokiol via Suzuki-Miyaura cross-coupling

Concise and practical synthesis of 4-O-methylhonokiol was achieved in 34% overall yield. The key features of our synthesis include chemoselective ortho-mono bromination of phenol as well as biaryl formation via Suzuki-Miyaura cross-coupling, in which bromophenol was reacted with potassium aryltrifluoroborate using Pd(OAc)2 and RuPhos under microwave conditions.