607-99-8 Usage
Chemical Properties
Off-White to Pale Yellow Solid
Uses
Different sources of media describe the Uses of 607-99-8 differently. You can refer to the following data:
1. 2,4,6-Tribromoanisole is suitable reagent used for the determination of 2,4,6-tribromoanisole in packaging materials and food by an analytical method based on multipleion detection GC-MS.
2. 2,4,6-Tribromoanisole is haloanisole often present in wine. 2,4,6-Tribromoanisole is one of the main agent responsible for the musty odor in wine sample
General Description
2,4,6-Tribromoanisole has been reported to cause cork taint in wines and vortex assisted liquid-liquid microextraction (VALLME) method for its determination has been developed. It is a musty-smelling metabolite of fungicide 2,4,6-tribromophenol. Determination of 2,4,6-trichloroanisole in wine at low ngL-1 levels by gas chromatography-high-resolution mass spectrometry (GC-HRMS) method has been repoted.
Check Digit Verification of cas no
The CAS Registry Mumber 607-99-8 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,0 and 7 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 607-99:
(5*6)+(4*0)+(3*7)+(2*9)+(1*9)=78
78 % 10 = 8
So 607-99-8 is a valid CAS Registry Number.
InChI:InChI=1/C7H5Br3O/c1-11-7-5(9)2-4(8)3-6(7)10/h2-3H,1H3
607-99-8Relevant articles and documents
Zwitterionic-Salt-Catalyzed Site-Selective Monobromination of Arenes
Xiong, Xiaodong,Tan, Fei,Yeung, Ying-Yeung
, p. 4243 - 4246 (2017/08/23)
A zwitterionic-salt-catalyzed electrophilic monobromination of arenes with high regioselectivity has been developed. Under mild reaction conditions, a wide range of monobrominated aromatic compounds can be obtained in excellent yields. The reaction can be operated using an extremely low catalyst loading (0.05 mol %) with the inexpensive brominating agent N-bromosuccinimide. The versatility of this catalytic protocol has been demonstrated by the scale-up reaction with a 0.01 mol % catalyst loading to provide the selectively halogenated compound in quantitative yield.
New synthesis of hydrangettn and collinin
Maes, Dominick,Vervisch, Stijn,De Kimpe, Norbert
, p. 395 - 415 (2008/02/07)
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SULFONYL ESTERS 1: THE REDUCTION OF TRIBROMOPHENYL SULFONATES WITH MERCAPTIDE ANIONS
Durkin, Kathleen Anne,Langler, Richard Francis,Morrison Nancy Ann
, p. 3070 - 3076 (2007/10/02)
2,4,6-tribromophenyl sulfonates have been shown to undergo unusually efficient reduction by mercaptide anions in hexamethylphosphoramide.The reduction products include the sulfinate anion derived from the sulfonate ester and the disulfide derived from the mercaptide anions.