114423-64-2

Basic information

• Product Name: trans,trans-3-(10'-acetoxy-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane
• Synonyms: trans,trans-3-(10'-acetoxy-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane
• CAS NO: 114423-64-2
• Molecular Weight: 597.083
• Mol File: 114423-64-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans,trans-3-(10'-acetoxy-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: trans,trans-3-(10'-acetoxy-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane(114423-64-2)
• EPA Substance Registry System: trans,trans-3-(10'-acetoxy-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane(114423-64-2)

Safety Data

• Hazardous Substances Data: 114423-64-2(Hazardous Substances Data)

Upstream product

• 26306-00-3 (6-bromohexyl)-trimethylsilyl ether 
• 114423-62-0 trans,trans-3-(6'-bromohexyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane 
• 114423-59-5 3-<6'-(trimethylsilyloxy)hexyl>-1-<(trimethylsilyl)oxy>cyclohexene 
• 114423-61-9 trans,trans-3-(6'-bromohexyl)-1,2-cyclohexanediol 
• 114423-60-8 trans,trans-3-(6-hydroxyhexyl)-1,2-cyclohexanediol 
• 4224-70-8 6-bromohexanoic acid 
• 4286-55-9 1-bromo-6-hexanol 
• 35435-68-8 4-acetoxy-1-butanol 
• 6564-95-0 4-oxobutyl acetate 
• 114423-63-1 <6'-(trans,trans-1'',2''-bis((dimethylthexylsilyl)oxy)-3''-cyclohexyl)hexyl>triphenylphosphonium bromide 

Downstream Products

• 114423-67-5 trans,trans-5-<9'-(2'',3''-bis((dimethylthexylsilyl)oxy)cyclohexyl)-3'-nonenyl>-3-methylenetetrahydro-2-furanone 
• 114423-68-6 trans,trans-5-<9'-(2'',3''-dihydroxycyclohexyl)-3'-nonenyl>-3-methylenetetrahydro-2-furanone 
• 114423-66-4 trans,trans-3-(10'-oxo-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane 
• 114423-65-3 trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane 

Relevant articles and documents

Synthesis of a Model Hapten with Cyclohexanediol and &α-Methylene-&γ-butyrolactone Groups, a Synthetic Analogue of Poison Ivy and Tulipalin Allergens Connected with a Carbon Chain

Potential skin sensitizers 1 and 1* with two different haptenic ends, (a) a cyclohexanediol group (saturated poison ivy analogue ) and (b) an α-methylene-γ-butyrolactone moiety (tulipalin A), separated by a nine carbon atoms chain containing a double bond have been prepared.The trans, trans relationship in the substituted cyclohexanediol was secured by a tandem Michael addition-hydroboration reaction.Contrary to an earlier example of a double-headed hapten containing pyrocatechol and α-methylene-γ-butyrolactone ends, the cyclohexanediol-α-methylene-γ-butyrolactone does not show any tolerance induction to the α-methylene-γ-butyrolactone end.It therefore seems that induction of tolerance as well as sensitization requires the formation of covalent bond with a protein carrier.