1151-98-0Relevant articles and documents
Novel pyrano and vinylphenol adducts of Deoxyanthocyanidins in sorghum sourdough
Bai, Yunpeng,Findlay, Brandon,Sanchez Maldonado, Alma Fernanda,Schieber, Andreas,Vederas, John C.,G?nzle, Michael G.
, p. 11536 - 11546 (2014)
This study determined the fate of deoxyanthocyanidins in sorghum sourdoughs. Sourdoughs prepared from the red sorghum variety Town were fermented with the caffeic acid-decarboxylating strains Lactobacillus plantarum FUA3171 and the decarboxylase negative
(±)-Diinsininone: made nature's way
Selenski, Carolyn,Pettus, Thomas R.R.
, p. 5298 - 5307 (2007/10/03)
We report the synthesis of diinsininone (33), the aglycone of (±)-diinsinin (2). Thereby, we complete the first construction of a proanthocyanidin (PA) type-A compound incorporating a [3.3.1]-bicyclic ketal as its characteristic core. Our strategy utilizes a coupling between a benzopyrilium salt and a flavanone that proves applicable to other PA type-A compounds. During this undertaking, treatment of naringenin (9) with 2-iodoxybenzoic acid (IBX) followed by reductive work-up affords eriodictyol (10). This reactivity mirrors that of catechol hydroxylase (F3H) found in the flavonoid pathway. Other interesting transformations include the formation of flavonoids through an ortho-quinone methide (o-QM) cycloaddition-oxidation sequence and regioselective β-glycosidations of several unprotected flavanones suggesting a likely synthesis of 2 from the aglycone 33.
Use of flavylium type compounds non-substituted in position 3 for dyeing keratinous fibres and compositions containing them
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, (2008/06/13)
The invention concerns the use of flavylium type compounds, non-substituted in position 3, and substituted by at least a hydroxyl or alcoxy radical, in particular Apigenidin, in pure form or in the form of plant extracts containing them, as coloring agent