115419-49-3Relevant articles and documents
The chemistry of pentavalent organobismuth reagents. Part 14. Recent advances in the copper-catalyzed phenylation of amines
Arnauld, Thomas,Barton, Derek H.R.,Doris, Eric
, p. 4137 - 4144 (1997)
A reinvestigation of the copper-mediated phenylation of amines by Bi(V) reagents is reported. The influence of the ligands bound to bismuth and the basicity of the amines have been examined. These results, combined with our previous observations, led to the development of a new system for the quantitative phenylation of selected hindered aliphatic and aromatic amines.
Reductive N-Arylethylation of Aromatic Amines and N-Heterocycles with Enol Ethers
V?gerl, Katharina,Ong, Duc Nghia,Bracher, Franz
, p. 1323 - 1330 (2017/12/26)
A convenient method for N-arylethylation of aromatic amines and heterocycles under mild reductive conditions was developed using (2-methoxyvinyl)(hetero)arenes as building blocks and triethylsilane/trifluoroacetic acid as reducing agent. This protocol is compatible with numerous functional groups, and aliphatic amines are inert due to protonation.
Efficient palladium-catalyzed amination of aryl chlorides using dicyclo-hexylamino[(2,6-dimethyl)morpholino]phenylphosphine as a PN2 ligand
Park, Song-Eun,Kang, Seung Beom,Jung, Kwang-Ju,Won, Ju-Eun,Lee, Sang-Gyeong,Yoon, Yong-Jin
experimental part, p. 815 - 823 (2009/07/11)
The palladium-catalyzed amination of aryl chlorides with various amines is accomplished using dicyclohexyl- amino[(2,6-dimethyl)morpholino]phenylphosphine as a bulky electron-rich monoaryl phosphine ligand. The optimized reaction conditions required the use of 1 mol% each of catalyst and ligand. Georg Thieme Verlag Stuttgart.