6308-98-1Relevant articles and documents
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Paty
, (1945)
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A potassium magnesiate complex: Synthesis, structure and catalytic intermolecular hydroamination of styrenes
Guan, Bing-Tao,Liu, Yu-Feng,Zhai, Dan-Dan,Zhang, Xiang-Yu
supporting information, (2022/01/19)
A new heterobimetallic potassium magnesiate complex KMg[N(SiMe3)2]2Bn (Bn = PhCH2-) was synthesized by simply mixing magnesium amide and potassium benzyl in toluene. The TMEDA-ligated potassium magnesiate comple
Method for synthesizing dibenzylamine compound by selective hydrogenation of photocatalytic benzonitrile compound
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Paragraph 0044-0047, (2021/09/29)
The invention belongs to the technical field of selective catalytic hydrogenation, and particularly relates to a method for synthesizing a dibenzylamine compound through selective hydrogenation of a photocatalytic benzonitrile compound, wherein the photocatalyst is prepared from silicon carbide with high specific surface area (specific surface area 20 - 100m). 2 Metal Platinum as a carrier load mass fraction 0.1-20%, the metal nanoparticles being less than 200 nanometers ?. g. After mixing the benzonitrile compound and the solvent at 0.01 - 0.6 mass ratio, the catalyst was added, and the hydrogen pressure was maintained between 0.1 mpa - 2 mpa under hydrogen atmosphere and the reaction was stirred while maintaining the temperature of the reaction system was 10 - 100 °C and the strength was 0.01 - 5W/cm. 2 Under the light intensity of the reaction 0.5 - 12h, the target product can be obtained. The method has the most remarkable characteristics of being capable of effectively utilizing light to promote reaction and high in reaction rate.
Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides
Luo, Jie,Rauch, Michael,Avram, Liat,Ben-David, Yehoshoa,Milstein, David
supporting information, p. 21628 - 21633 (2021/01/11)
Direct hydrogenation of thioesters with H2 provides a facile and waste-free method to access alcohols and thiols. However, no report of this reaction is documented, possibly because of the incompatibility of the generated thiol with typical hydrogenation catalysts. Here, we report an efficient and selective hydrogenation of thioesters. The reaction is catalyzed by an acridine-based ruthenium complex without additives. Various thioesters were fully hydrogenated to the corresponding alcohols and thiols with excellent tolerance for amide, ester, and carboxylic acid groups. Thiocarbamates and thioamides also undergo hydrogenation under similar conditions, substantially extending the application of hydrogenation of organosulfur compounds.