1155878-27-5Relevant articles and documents
Palladium-catalyzed direct α-arylation of α-fluoroketones: A straightforward route to α-fluoro-α-arylketones
Guo, Chen,Wang, Ruo-Wen,Guo, Yong,Qing, Feng-Ling
experimental part, p. 86 - 96 (2012/02/05)
The palladium-catalyzed direct α-arylation of both open-chain and cyclic α-fluoroketones by using P(o-tolyl)3 or RuPhos as ligand and K3PO4·3H2O as mild base has been developed. This method allows a variety of q
Pd-catalyzed arylation of silyl enol ethers of substituted α-fluoroketones
Guo, Yong,Twamley, Brendan,Shreeve, Jean'Ne M.
experimental part, p. 1716 - 1722 (2009/06/28)
α-Fluoro-α-aryl-ketones were synthesized by the Pd-catalyzed cross-coupling of aryl bromides with either α-fluoroketones or their corresponding silyl enol ethers. The direct arylation with an α-fluoroketone requires a strong base, such as potassium tert-b