115693-78-2

Basic information

• Product Name: 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose
• CAS NO: 115693-78-2
• Molecular Weight: 380.438
• Mol File: 115693-78-2.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(115693-78-2)
• EPA Substance Registry System: 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(115693-78-2)

Safety Data

• Hazardous Substances Data: 115693-78-2(Hazardous Substances Data)

Upstream product

• 105-13-5 4-Methoxybenzyl alcohol 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 2746-25-0 p-Methoxybenzyl bromide 
• 2595-05-3 Diacetone D-glucose 
• 824-94-2 p-methoxybenzyl chloride 
• 14686-89-6 (1,2:5,6)-di-O-isopropylidene-D-gulose 
• 1450734-54-9 4-methoxybenzyl N-phenyl-2,2,2-trifluoroacetimidate 
• 937184-70-8 2-(4-methoxybenzyloxy)-4-methylquinoline 
• 99605-27-3 3-O-(tert-butyldimethylsilyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 13964-22-2 3-O-benzoyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 350848-02-1 2-[(4-methoxybenzyl)oxy]-3-nitropyridine 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 

Downstream Products

• 109536-51-8 1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-α-D-glucofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 123-11-5 4-methoxy-benzaldehyde 
• 69940-04-1 (R)-1-[(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol 
• 1384188-37-7 6-bromo-6-deoxy-1,2-O-isopropylidene-3-O-(p-methoxybenzyl)-α-D-glucofuranose 
• 1384188-56-0 5-(p-bromobenzoyl)-3-(α-D-xylofuranos-5-ulo-5-yl)imidazo[2,1-b]thiazole 
• 1384188-60-6 5-(p-bromobenzoyl)-3-(β-D-xylofuranos-5-ulo-5-yl)imidazo[2,1-b]thiazole 
• 1384188-55-9 5-(p-chlorobenzoyl)-3-(α-D-xylofuranos-5-ulo-5-yl)imidazo[2,1-b]thiazole 
• 1384188-59-3 5-(p-chlorobenzoyl)-3-(β-D-xylofuranos-5-ulo-5-yl)imidazo[2,1-b]thiazole 
• 1384188-54-8 3-(p-bromobenzoyl)-5-(α-D-xylofuranos-5-ulo-5-yl)imidazo[2,1-b]thiazole 
• 1384188-58-2 3-(p-bromobenzoyl)-5-(β-D-xylofuranos-5-ulo-5-yl)imidazo[2,1-b]thiazole 

Relevant articles and documents

A practical method for p -methoxybenzylation of hydroxy groups using 2,4,6-tris(p -methoxybenzyloxy)-1,3,5-triazine (TriBOT-PM)

A new acid-catalyzed p-methoxybenzylating reagent, 2,4,6-tris(p- methoxybenzyloxy)-1,3,5-triazine (TriBOT-PM), has been developed. The reaction of acid- and alkali-labile alcohols with TriBOT-PM in the presence of a catalytic amount of various acids (TfOH, BF3·OEt2, CSA, etc.) afforded the corresponding p-methoxybenzyl ethers in good yields. Since TriBOT-PM is an air-stable crystalline solid and can be prepared from inexpensive materials, i.e. cyanuric chloride and anisyl alcohol, this route is of practical use. Georg Thieme Verlag Stuttgart, New York.

An efficient means for generating p-methoxybenzyl (PMB) ethers under mildly acidic conditions

The protection of a wide variety of alcohols as their p-methoxybenzyl ethers can be performed with PMBO-lepidine in the presence of methyl tosylate or, preferably, camphorsulfonic acid. No inorganic promoters are required, thereby facilitating workup and product isolation. Georg Thieme Verlag Stuttgart.

An efficient method for the p-methoxybenzylation of hydroxy groups with 2-(4-methoxybenzyloxy)-3-nitropyridine

2-(4-Methoxybenzyloxy)-3-nitropyridine (PMBONPy), easily prepared from 2-chloro-3-nitropyridine and p-methoxybenzyl (PMB) alcohol, reacts with various types of hydroxy groups in the presence of a catalytic amount of trimethylsilyl triflate (Me3SiOTf) to give the corresponding PMB ethers in high yields under mild conditions.