118460-39-2Relevant articles and documents
Rhodium-catalyzed Reformatsky-type reaction of ethyl bromodifluoroacetate
Sato, Kazuyuki,Tarui, Atsushi,Kita, Tetsuya,Ishida, Yoshitaka,Tamura, Hanae,Omote, Masaaki,Ando, Akira,Kumadaki, Itsumaro
, p. 5735 - 5737 (2004)
Treatment of a variety of carbonyl compounds with ethyl bromodifluoroacetate and Et2Zn in the presence of RhCl(PPh 3)3 in CH3CN afforded Reformatsky-type products in good to excellent yields in a mild reaction c
Synthesis of Enantioenriched α,α-Dichloro- and α,α-Difluoro-β-Hydroxy Esters and Amides by Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation
Zheng, Long-Sheng,Phansavath, Phannarath,Ratovelomanana-Vidal, Virginie
supporting information, p. 5107 - 5111 (2018/09/13)
A mild and convenient approach was developed to prepare a series of α,α-dihalogeno β-hydroxy esters or amides by using commercially available Noyori's complex [RuCl(p-cymene)(R,R)-TsDPEN] as a catalyst (S/C = 100?200) in the asymmetric transfer hydrogenat
Nickel-Catalyzed Reductive Cross-Coupling of (Hetero)Aryl Iodides with Fluorinated Secondary Alkyl Bromides
Li, Xuefei,Jiang, Zhong-Xing,Feng, Zhang,Zhang, Xingang
supporting information, p. 5570 - 5573 (2015/12/17)
A mild and efficient nickel-catalyzed reductive cross-coupling between fluorinated secondary alkyl bromides and (hetero)aryl iodides is described. The use of FeBr2 as an additive successfully overcomes the hydrodebromination and β-fluorine elim
