1184934-40-4

Basic information

• Product Name: 4-azidobutyl benzoate
• Synonyms: 4-azidobutyl benzoate
• CAS NO: 1184934-40-4
• Molecular Weight: 219.243
• Mol File: 1184934-40-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 4-azidobutyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-azidobutyl benzoate(1184934-40-4)
• EPA Substance Registry System: 4-azidobutyl benzoate(1184934-40-4)

Safety Data

• Hazardous Substances Data: 1184934-40-4(Hazardous Substances Data)

Upstream product

• 18203-32-2 3-butenyl benzoate 
• 54953-78-5 4-azido-1-butanol 
• 98-88-4 benzoyl chloride 
• 19097-44-0 4-iodobutylbenzoate 
• 946-02-1 4-chlorobutyl benzoate 

Downstream Products

• 1263067-92-0 4-(4-((tert-butyldimethylsilyloxy)methyl)-1H-1,2,3-triazol-1-yl)butyl benzoate 

Relevant articles and documents

A formal synthesis of swainsonine by gold-catalyzed allene cyclization

Image Presented A formal synthesis of swainsonine has been achieved using a highly efficient and diastereoselective gold(III)-catalyzed allene cyclization.

ENVIRONMENTALLY-FRIENDLY HYDROAZIDATION OF OLEFINS

The present invention provides processes for the synthesis of organic azides, intermediates for the production thereof, and compositions related thereto.

Dual Photoredox/Copper Catalysis for the Remote C(sp3)?H Functionalization of Alcohols and Alkyl Halides by N-Alkoxypyridinium Salts

Under mild dual photoredox/copper catalysis, the reaction of N-alkoxypyridinium salts with readily available silyl reagents (TMSN3, TMSCN, TMSNCS) afforded δ-azido, δ-cyano, and δ-thiocyanato alcohols in high yields. The reaction went through a domino process involving alkoxy radical generation, 1,5-hydrogen atom transfer (1,5-HAT) and copper-catalyzed functionalization of the resulting C-centered radical. Conditions for catalytic enantioselective δ-C(sp3)?H cyanation were also documented.