1187560-41-3

Basic information

• Product Name: C₁₆H₂₂O₂
• Synonyms: C₁₆H₂₂O₂
• CAS NO: 1187560-41-3
• Molecular Weight: 246.349
• Mol File: 1187560-41-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₂₂O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₂₂O₂(1187560-41-3)
• EPA Substance Registry System: C₁₆H₂₂O₂(1187560-41-3)

Safety Data

• Hazardous Substances Data: 1187560-41-3(Hazardous Substances Data)

Upstream product

• 61393-94-0 (R)-2-benzyloxirane 
• 80783-98-8 N-methoxy-N-methylcyclohexanecarboxamide 
• 1187560-42-4 C₁₅H₁₆OS 
• 29338-96-3 N-(cyclohexylcarbonyl)morpholine 

Relevant articles and documents

Polyol synthesis with β-Oxyanionic alkyllithium Reagents: Syntheses of aculeatins A, B, and D

Synthesis of ketone aldol products using a non-aldol route was developed. The β-phenylthio alcohols were prepared from optically pure oxiranes. Deprotonation and reductive lithiation generated the key intermediate, a β-oxyanionic alkyllithium reagent. Addition to a Weinreb amide produced the β-hydroxy ketone In >90% yield using only 1.5 equiv of the phenylthio alcohol. Stereoselective reduction of the ketone led to either the syn-or anti-1,3-diol. This simple, convergent sequence was used to prepare aculeatins A, B, and D from a common intermediate