1187560-42-4

Basic information

• Product Name: C₁₅H₁₆OS
• Synonyms: C₁₅H₁₆OS
• CAS NO: 1187560-42-4
• Molecular Weight: 244.357
• Mol File: 1187560-42-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₆OS(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₆OS(1187560-42-4)
• EPA Substance Registry System: C₁₅H₁₆OS(1187560-42-4)

Safety Data

• Hazardous Substances Data: 1187560-42-4(Hazardous Substances Data)

Upstream product

• 61393-94-0 (R)-2-benzyloxirane 
• 108-98-5 thiophenol 

Downstream Products

• 1187560-41-3 C₁₆H₂₂O₂ 
• 1187560-43-5 C₁₃H₂₀O₂ 

Relevant articles and documents

Polyol synthesis with β-Oxyanionic alkyllithium Reagents: Syntheses of aculeatins A, B, and D

Synthesis of ketone aldol products using a non-aldol route was developed. The β-phenylthio alcohols were prepared from optically pure oxiranes. Deprotonation and reductive lithiation generated the key intermediate, a β-oxyanionic alkyllithium reagent. Addition to a Weinreb amide produced the β-hydroxy ketone In >90% yield using only 1.5 equiv of the phenylthio alcohol. Stereoselective reduction of the ketone led to either the syn-or anti-1,3-diol. This simple, convergent sequence was used to prepare aculeatins A, B, and D from a common intermediate