1190207-25-0

Basic information

• Product Name: (S)-N-tert-butoxycarbonyl-2-[bis(2-methylphenyl)phosphinomethyl]pyrrolidine
• Synonyms: (S)-N-tert-butoxycarbonyl-2-[bis(2-methylphenyl)phosphinomethyl]pyrrolidine
• CAS NO: 1190207-25-0
• Molecular Weight: 397.497
• Mol File: 1190207-25-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-N-tert-butoxycarbonyl-2-[bis(2-methylphenyl)phosphinomethyl]pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-tert-butoxycarbonyl-2-[bis(2-methylphenyl)phosphinomethyl]pyrrolidine(1190207-25-0)
• EPA Substance Registry System: (S)-N-tert-butoxycarbonyl-2-[bis(2-methylphenyl)phosphinomethyl]pyrrolidine(1190207-25-0)

Safety Data

• Hazardous Substances Data: 1190207-25-0(Hazardous Substances Data)

Upstream product

• 36042-94-1 bis(o-tolyl)chlorophosphine 
• 128542-75-6 (S)-2-(bromomethyl)-1-<(tert-butyloxy)carbonyl>pyrrolidine 
• 86661-32-7 (S)-tert-butyl 2-((tosyloxy)methyl)pyrrolidine-1-carboxylate 

Downstream Products

• 1190207-28-3 tert-butyl N-{1-(R)-[(2-(S)-bis(2-methylphenyl)phosphinomethyl)pyrrolidine-1-carbonyl]-2-methylpropyl}-carbamate 
• 1190207-26-1 tert-butyl N-{1-(S)-[(2-(S)-bis(2-methylphenyl)phosphinomethyl)pyrrolidine-1-carbonyl]-2-methylpropyl}-carbamate 
• 1190207-30-7 (S)-N-tert-butylcarbonyl-2-[bis(2-methylphenyl)phosphinomethyl]pyrrolidine 
• 1352663-15-0 (S)-2-[(di-o-tolylphosphino)methyl]-N,N-diisopropylpyrrolidine-1-carboxamide 

Relevant articles and documents

Proline-based P,O ligand/iridium complexes as highly selective catalysts: Asymmetric hydrogenation of trisubstituted alkenes

P,O joins the mix: P,O ligands (L1) form efficient iridium catalysts for the asymmetric hydrogenation of olefins. The proline-derived ligands lead to high enantioselectivities with several classes of alkenes, most notably with α,β-unsaturated carboxylic e