119244-66-5

Basic information

• Product Name: l-menthyl (trimethylsilyl)propanoate
• CAS NO: 119244-66-5
• Molecular Weight: 284.514
• Mol File: 119244-66-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: l-menthyl (trimethylsilyl)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: l-menthyl (trimethylsilyl)propanoate(119244-66-5)
• EPA Substance Registry System: l-menthyl (trimethylsilyl)propanoate(119244-66-5)

Safety Data

• Hazardous Substances Data: 119244-66-5(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 29066-36-2 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl propionate 

Downstream Products

• 119244-55-2 (R)-2-Methyl-1,3-diphenyl-2-trimethylsilanyl-propan-1-ol 
• 112297-89-9 (R)-(+)-1,3-diphenyl-2-methyl-2-(trimethylsilyl)-1-propanone 
• 119323-96-5 (R)-(-)-2-methyl-2-(trimethylsilyl)-3-phenylpropanol 
• 119244-54-1 (R)-(-)-2-methyl-2-(trimethylsilyl)-3-phenylpropanal 
• 112297-91-3 (R)-(+)-1,4-diphenyl-2-methyl-2-(trimethylsilyl)-1-butanone 
• 119244-69-8 (R)-(-)-2-methyl-2-(trimethylsilyl)-4-phenylbutanol 
• 112297-80-0 l-menthyl 2-methyl-2-(trimethylsilyl)-3-phenylpropionate 
• 112297-84-4 l-menthyl 2-methyl-2-(trimethylsilyl)-3-phenylpropionate 

Relevant articles and documents

Cleavage of Carbon-Carbon Bonds with High Stereochemical Control. 6. Asymmetric Synthesis of Chiral C-Centered Organosilanes by Haller-Bauer Cleavage of Optically Active, Nonenolizable α-Silyl Phenyl Ketones

Sequential alkylation and methylation of l-menthyl ester 10 provides diastereomeric mixtures in which 12 is slighthly enhanced over 13.Conversely, C-silation and alkylation of propionate ester 11 delivers 13 in excess.In either cause, a single chromatogra