119267-77-5

Basic information

• Product Name: S-acetyl-2-mercapto-4’-methoxyacetophenone
• Synonyms: S-acetyl-2-mercapto-4’-methoxyacetophenone
• CAS NO: 119267-77-5
• Molecular Weight: 224.28
• Mol File: 119267-77-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: S-acetyl-2-mercapto-4’-methoxyacetophenone(CAS DataBase Reference)
• NIST Chemistry Reference: S-acetyl-2-mercapto-4’-methoxyacetophenone(119267-77-5)
• EPA Substance Registry System: S-acetyl-2-mercapto-4’-methoxyacetophenone(119267-77-5)

Safety Data

• Hazardous Substances Data: 119267-77-5(Hazardous Substances Data)

Upstream product

• 2632-13-5 2-Bromo-4'-methoxyacetophenone 
• 507-09-5 tiolacetic acid 
• 53271-44-6 S-(4-methylphenyl) thio(4-methoxybenzoate) 
• 100-09-4 4-methoxybenzoic acid 
• 67-64-1 acetone 
• 10387-40-3 potassium thioacetate 

Downstream Products

• 100-09-4 4-methoxybenzoic acid 
• 139488-44-1 mercapto-1-(4’-methoxyphenyl)ethanone 
• 50834-78-1 methyl 4-(2-methyl-1,3-thiazol-4-yl)phenyl ether 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 7347-70-8 N-[4-(4-methoxy-phenyl)-4-oxo-butyl]-phthalimide 
• 61022-41-1 1-(4-methoxyphenyl)-5-phenylpentan-1-one 
• 62170-25-6 1-(4-methoxyphenyl)octan-1-one 
• 805240-60-2 6-hydroxy-1-(4-methoxyphenyl)hexan-1-one 
• 149109-18-2 6-acetoxy-1-(4-methoxyphenyl)hexan-1-one 
• 616226-79-0 (5-oxo-5-(4-methoxyphenyl)-pentyl)-carbamic acid tert-butyl ester 
• 24188-99-6 2-cyclopentyl-1-(4-methoxyphenyl)ethan-1-one 

Relevant articles and documents

Br?nsted-base-catalyzed remote cascade reactivity of 2,4-dienones-asymmetric synthesis of tetrahydrothiophenes

This study demonstrates that the remote cascade functionalization of 2,4-dienones can be realized by employing Br?nsted base catalysis. The developed cascade involving 1,6-addition followed by the intramolecular aldol reaction provides a straightforward a

Intermolecular Phosphite-Mediated Radical Desulfurative Alkene Alkylation Using Thiols

We report herein the development of a S atom transfer process using triethyl phosphite as the S atom acceptor that allows thiols to serve as precursors of C-centered radicals. A range of functionalized and electronically unbiased alkenes including those containing common heteroatom-based functional groups readily participate in this reductive coupling. This process is driven by the exchange of relatively weak S-H and C-S bonds of aliphatic thiols for C-H, C-C, and S-P bonds of the products formed.

Synthesis of 2-Aminoazoles from Thioesters via α-Heterosubstituted Ketones by Copper-Mediated Cross-Coupling

Facile synthesis of a variety of α-heterosubstituted ketones under mild conditions was achieved by copper-mediated cross-coupling of thioesters with functionalized organostannanes. Application of this coupling methodology provided a concise pathway for the conversion of carboxylic acids to 2-aminoimidazoles, 2-aminothiazoles, and 2-aminooxazoles via thioesters in practical yields.