119405-65-1

Basic information

• Product Name: Tributyl(3-thienyl)tin
• Synonyms: 3-(Tributyltin)thiophene;Tributyl(3-thienyl)stannane;Tributyl(3-thienyl)tin
• CAS NO: 119405-65-1
• Molecular Formula: C₁₆H₃₀SSn
• Molecular Weight: 373.1844
• Mol File: 119405-65-1.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Tributyl(3-thienyl)tin(CAS DataBase Reference)
• NIST Chemistry Reference: Tributyl(3-thienyl)tin(119405-65-1)
• EPA Substance Registry System: Tributyl(3-thienyl)tin(119405-65-1)

Safety Data

• Hazardous Substances Data: 119405-65-1(Hazardous Substances Data)

Upstream product

• 872-31-1 3-Bromothiophene 
• 1461-22-9 tributyltin chloride 
• 1067-52-3 tributyltin methoxide 
• 813-19-4 bis(tri-n-butyltin) 
• 14596-83-9 3-thiophenecarboxylic acid phenyl ester 
• 17955-46-3 trimethylsilyltributyltin 

Downstream Products

• 62119-77-1 1-(thiophen-3-yl)propan-2-one 
• 98-03-3 thiophene-2-carbaldehyde 
• 2404-87-7 3-phenylthiophene 
• 82437-75-0 3-(4-methoxy-phenyl)-thiophene 
• 473693-79-7 ethyl 4-oxo-4-(3-thienyl)butanoate 
• 172507-33-4 4-(thiophen-3-yl)benzonitrile 
• 53091-09-1 ethyl 2-oxo-2-(thiophen-3-yl)acetate 
• 28560-79-4 3-(4-nitrophenyl)thiophene 
• 21298-55-5 3-(2-pyridyl)thiophene 
• 21308-81-6 3-(thiophen-3-yl)pyridine 
• 160278-20-6 3-(4-hydroxymethyl-phenyl)thiophene 
• 740803-22-9 3-(2,5-dimethoxyphenyl)thiophene 
• 887256-73-7 3-(2,5-dimethoxyphenyl)-2,2'-bithiophene 
• 1356391-12-2 3-(3,5-dibromophenyl)thiophene 

Relevant articles and documents

Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters

An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common esters including ethyl, cyclohexyl, benzyl, and phenyl esters can undergo the newly developed decarbonylative stannylation reaction. The reaction shows broad substrate scope, can differentiate between different types of esters, and if applied in consecutive fashion, allows the transformation of methyl esters into aryl fluorides or biaryls via fluororination or arylation.

Tetraphenylmethane or silane-based compound as well as preparation method and application thereof

The invention provides a tetraphenylmethane or silane-based compound shown in formula (I), a preparation method of the tetraphenylmethane or silane-based compound and application of the tetraphenylmethane or silane-based compound in synthesizing an electrochromic material membrane as a monomer. As the tetraphenylmethane or silane-based compound has a space structure of tetrahedral tetrad, through membrane formation with electrochemcial polymerization, the obtained membrane expresses larger specific surface area and good electrochemical performance such as electrochromism and the like at the same time. The contrast of the membrane is 30-80 percent, the response time of the membrane is between 0.5s and 6s, the contrast and the response time both express reasonable electrochemcial stable activity, and experimental results show that the material is a potential electrochromic material. The formula of the tetraphenylmethane or silane-based compound is shown in the description.

Stannyl-Lithium: A Facile and Efficient Synthesis Facilitating Further Applications

We have developed a highly efficient, practical, polycyclic aromatic hydrocarbon (PAH)-catalyzed synthesis of stannyl lithium (Sn-Li), in which the tin resource (stannyl chloride or distannyl) is rapidly and quantitatively transformed into Sn-Li reagent at room temperature without formation of any (toxic) byproducts. The resulting Sn-Li reagent can be stored at ambient temperature for months and shows high reactivity toward various substrates, with quantitative atom efficiency.