119461-42-6

Basic information

• Product Name: (S)-N-(p-toluenesulfonyl)-4-amino-1-Z-(trimethylsilyl)-1-pentene
• Synonyms: (S)-N-(p-toluenesulfonyl)-4-amino-1-Z-(trimethylsilyl)-1-pentene
• CAS NO: 119461-42-6
• Molecular Weight: 311.52
• Mol File: 119461-42-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-N-(p-toluenesulfonyl)-4-amino-1-Z-(trimethylsilyl)-1-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-(p-toluenesulfonyl)-4-amino-1-Z-(trimethylsilyl)-1-pentene(119461-42-6)
• EPA Substance Registry System: (S)-N-(p-toluenesulfonyl)-4-amino-1-Z-(trimethylsilyl)-1-pentene(119461-42-6)

Safety Data

• Hazardous Substances Data: 119461-42-6(Hazardous Substances Data)

Upstream product

• 119461-40-4 S-(+)-2-methyl-N-p-tosylaziridine 
• 88129-44-6 (S)-N-(p-toluenesulfonyl)-2-amino-1-propyl p-toluenesulfonate 
• 119461-41-5 (S)-N-(p-toluenesulfonyl)-4-amino-1-(trimethylsilyl)-1-pentyne 

Downstream Products

• 119461-54-0 rac-trans-N-(ethoxycarbonyl)-6-methyl-2-phenyl-1,2,5,6-tetrahydropyridine 
• 119461-54-0 rac-cis-N-(ethoxycarbonyl)-6-methyl-2-phenyl-1,2,5,6-tetrahydropyridine 
• 119461-45-9 rac-cis 6-methyl-2-phenyl-1,2,5,6-tetrahydropyridines 
• 119461-45-9 rac-trans 6-methyl-2-phenyl-1,2,5,6-tetrahydropyridines 
• 119461-53-9 (Ethoxy-phenyl-methyl)-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-carbamic acid ethyl ester 
• 119461-49-3 rac-trans-N-benzyl-6-methyl-2-phenyl-1,2,5,6-tetrahydropyridine 
• 119461-44-8 ((Z)-(S)-1-Methyl-4-trimethylsilanyl-but-3-enyl)-[1-phenyl-meth-(E)-ylidene]-amine 
• 119461-52-8 rac-trans-N-methyl-6-methyl-2-phenyl-1,2,5,6-tetrahydropyridine 
• 153681-98-2 N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide 
• 3197-42-0 (S)-2-methylpiperidine 
• 153682-00-9 Benzyl-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-trimethylsilanylmethyl-amine 
• 153682-03-2 (S)-1-Benzyl-2-methyl-1,2,3,6-tetrahydro-pyridine 
• 88034-71-3 (+)-(S)-2-methylpiperidinyl-(R)-2-methoxy-2-phenyl-3,3,3-trifluoropropanamide 
• 153681-99-3 (S)-N-benzyl-N-(Z)-(1-methyl-4-trimethylsilylbut-3-enyl)amine 

Relevant articles and documents

SYNTHESIS OF SUBSTITUTED TETRAHYDROPYRIDINES BY CYCLIZATIONS OF SILICON-CONTAINING IMINIUM IONS

Trans-2,6-disubstituted-1,2,5,6-tetrahydropyridines are formed stereoselectively from the cyclization of silicon-containing iminium cations 5 if the nitrogen substituents R1 is an alkyl group.In contrast, cyclization of the corresponding NH or N-acyl iminium ions occurs in a stereorandom fashion.Nonracemic tetrahydropyridines cannot be prepared in this way, since both iminium ion and N-acyliminium ion intermediates racemize prior to cyclization.