153681-99-3

Basic information

• Product Name: (S)-N-benzyl-N-(Z)-(1-methyl-4-trimethylsilylbut-3-enyl)amine
• Synonyms: (S)-N-benzyl-N-(Z)-(1-methyl-4-trimethylsilylbut-3-enyl)amine
• CAS NO: 153681-99-3
• Molecular Weight: 247.456
• Mol File: 153681-99-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-N-benzyl-N-(Z)-(1-methyl-4-trimethylsilylbut-3-enyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-benzyl-N-(Z)-(1-methyl-4-trimethylsilylbut-3-enyl)amine(153681-99-3)
• EPA Substance Registry System: (S)-N-benzyl-N-(Z)-(1-methyl-4-trimethylsilylbut-3-enyl)amine(153681-99-3)

Safety Data

• Hazardous Substances Data: 153681-99-3(Hazardous Substances Data)

Upstream product

• 119461-43-7 (S)-4-amino-1-(trimethylsilyl)-1-pentyne 
• 98-88-4 benzoyl chloride 
• 100-52-7 benzaldehyde 
• 100-39-0 benzyl bromide 
• 119461-42-6 (S)-N-(p-toluenesulfonyl)-4-amino-1-Z-(trimethylsilyl)-1-pentene 
• 81939-73-3 (2S)-2-hydroxypent-4-yne 
• 100-46-9 benzylamine 
• 153681-98-2 N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide 
• 119461-44-8 ((Z)-(S)-1-Methyl-4-trimethylsilanyl-but-3-enyl)-[1-phenyl-meth-(E)-ylidene]-amine 

Downstream Products

• 88034-71-3 (+)-(S)-2-methylpiperidinyl-(R)-2-methoxy-2-phenyl-3,3,3-trifluoropropanamide 
• 3197-42-0 (S)-2-methylpiperidine 
• 119461-49-3 rac-trans-N-benzyl-6-methyl-2-phenyl-1,2,5,6-tetrahydropyridine 
• 153682-00-9 Benzyl-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-trimethylsilanylmethyl-amine 
• 119461-47-1 [Benzyl-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-amino]-phenyl-acetonitrile 
• 40240-12-8 1-benzyl-1,2,3,6-tetrahydropyridine 
• 153682-03-2 (S)-1-Benzyl-2-methyl-1,2,3,6-tetrahydro-pyridine 
• 109838-90-6 N-benzyl-(E)-4-(trimethylsilyl)-3-buten-1-ylamine 

Relevant articles and documents

Rapid access to trans-2,6-disubstituted piperidines: Expedient total syntheses of (-)-solenopsin A and (+)-epi-dihydropinidine

Expedient syntheses of (-)-solenopsin A and (+)-epi-dihydropinidine are reported, the key step in both being the one-pot multicomponent aza-silyl-Prins condensation reaction to yield a trans dihydropyridine. Georg Thieme Verlag Stuttgart.

Preparation of enantioenriched tetrahydropyridines by iminium ion-vinylsilane cyclizations

Tetrahydropyridines can be prepared from (S)-amino acids in high enantiomeric purity as outlined in equation 1.