119946-86-0Relevant articles and documents
Rate increases in the fluorination of bulky chlorosilanes caused by ultrasound or by water
Lickiss, Paul D.,Lucas, Ronan
, p. 167 - 172 (1996)
The conversion of bulky chlorosilanes to fluorosilanes under anhydrous conditions with hexafluorosilicate salts is accelerated by ultrasound. The fluorination of sterically hindered chlorosilanes such as tBuPh2SiCl, in the absence of ultrasound, is greatly accelerated by the addition of water to the reaction mixture.
Novel Hydrolysis Pathways of Dimesityldifluorosilane via an Anionic Five-Coordinated Silicate and a Hydrogen-Bonded Bisilonate. Model Intermediates in the Sol-Gel Process
Johnson, Stephen E.,Deiters, Joan A.,Day, Roberta O.,Holmes, Robert R.
, p. 3250 - 3258 (2007/10/02)
Reaction of dimesityldifluorosilane, Mes2SiF2, with Et4NF*2H2O in acetonitrile resulted in the formation of the five-coordinated complexes, , , the hydrogen bisilonate, 2 (2), and the disiloxane, (Mes2Si